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In relation to this article, we declare that there is no conflict of interest.
Publication history
Received August 27, 2025
Revised December 3, 2025
Accepted December 23, 2025
Available online April 5, 2026
articles This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
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Anisotropic Etching of Cobalt Thin Films Using High Density Plasma of Ethylenediamine/Ar Gas Mixture

Department of Chemistry and Chemical Engineering , Inha University 1Program in Semiconductor Convergence , Inha University
cwchung@inha.ac.kr
Korean Journal of Chemical Engineering, April 2026, 43(5), 1415-1424(10)
https://doi.org/10.1007/s11814-025-00634-7

Abstract

 Dry etching of Co thin fi lms patterned with TiN hard marks was conducted using a high-density plasma of ethylenediamine/Ar

gas mixture. The eff ects of ethylenediamine concentration on the etch characteristics of the Co thin fi lms were 

examined. In addition, the main etch parameters were investigated in terms of the etch rate, etch selectivity, and the etch 

profi le. Scanning probe microscopy, optical emission spectroscopy, and X-ray photoelectron spectroscopy (XPS) were 

utilized to elucidate the etch mechanism in ethylenediamine/Ar gas chemistry. XPS analysis confi rmed the formation of 

Co(CN) 2 during the etching. Finally, the redeposition-free anisotropic etching of Co thin fi lms patterned with 150 nm lines 

were achieved using an ethylenediamine/Ar gas mixture. 

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