Overall
- Language
- English
- Conflict of Interest
- In relation to this article, we declare that there is no conflict of interest.
- Publication history
-
Received August 29, 2025
Revised October 15, 2025
Accepted October 17, 2025
Available online January 26, 2026
-
This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
Most Cited
Isobaric Vapor-Liquid Equilibrium for Binary Systems of Ethyl Methyl Carbonate (and Diethyl Carbonate) + Ethyl Propionate, + Methyl Propionate at 101.3 kPa
https://doi.org/10.1007/s11814-025-00589-9
Abstract
Isobaric vapor-liquid equilibrium (VLE) data were measured four binary mixtures of ethyl methyl carbonate (EMC) + methyl
propionate (MP), EMC + ethyl propionate (EP), diethyl carbonate (DEC) + MP, and DEC + EP at 101.3 kPa. The experimental
VLE data for four binary systems were correlated with the Wilson, NRTL, and UNIQUAC activity coefficient
models to obtain the interaction binary parameters, respectively. These model parameters were obtained by minimizing
a maximum likelihood objective function. The thermodynamic consistency of the experimental data was tested using the
Redlich-Kister method and the Fredenslund method, which indicated that the experimental data satisfy the consistency
tests. The results associated with the three models agree well with the experimental data, and no azeotropic behavior was
observed in these binary systems.
