Overall
- Language
- English
- Conflict of Interest
- In relation to this article, we declare that there is no conflict of interest.
- Publication history
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Received August 14, 2024
Accepted February 15, 2025
Available online May 25, 2025
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This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
Most Cited
Zinc Recovery from Fly Ash for Preparation of a Porous Metal–Carbon Composite (PMCC) using Pyrolysis of Zinc-Terephthalate Composite: Adsorption of Bisphenol a from Contaminated Waters
https://doi.org/10.1007/s11814-025-00421-4
Abstract
This research presents a groundbreaking approach to address water contamination by Bisphenol A (BPA) using a sustainable
and environmentally friendly porous metal–carbon composite (PMCC) derived from municipal solid waste incineration
(MSWI) remnants. The study focuses on extracting of zinc (Zn) from MSWI fl y ash, and subsequently utilizing the
recovered metal for synthesizing an innovative PMCC. The composite with a high surface area (225.6 m 2 g −1 ) demonstrates
remarkable effi ciency in adsorbing BPA, a signifi cant water pollutant with adverse health eff ects. The successful preparation
of the composite was confi rmed by various analytical techniques, including FTIR, FESEM, XRD, and BET. The research
employs response surface methodology to optimize the removal process and validates the model through statistical analysis.
Maximum removal effi ciency of 99.6% was achieved under the optimal values for adsorbent and reaction time of 0.862 g L −1
and 50 min, respectively, for BPA with a concentration of 23.8 mg L −1 . Additionally, this study investigated BPA adsorption
isotherms and kinetic models, revealing the Langmuir isotherm and pseudo-second-order kinetic model as the most
appropriate models for characterizing the adsorbent behavior. The regeneration and reusability of the PMCC were explored,
indicating its potential for industrial applications. Overall, this research pioneers a sustainable approach to water treatment
by integrating waste-derived material into the synthesizing of eff ective adsorbents for environmental remediation.

