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Conflict of Interest
In relation to this article, we declare that there is no conflict of interest.
Publication history
Received September 30, 2024
Accepted January 9, 2025
Available online May 25, 2025
articles This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
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Most Cited

Bi 2 O 3 Modifi ed Floatable Hollow Glass Microspheres Supported TiO 2 to Construct II-Scheme Heterojunction for Photocatalytic Degradation of Tetracycline Hydrochloride

Southwest Jiaotong University
Korean Journal of Chemical Engineering, May 2025, 42(5), 1003-1013(11)
https://doi.org/10.1007/s11814-025-00390-8

Abstract

 Photocatalysis technology has garnered signifi cant attentions for addressing water pollution issues, however, conventional 

photocatalysts face great challenges such as poor recoverability, low light utilization rates, and severe caking that hinder their 

widespread use. This study presents the development of fl oating Bi 2 O 3 /TiO 2 /HGM (BTH) photocatalysts utilizing hollow 

glass microspheres (HGM) as a supporting material. The optimized heterojunction of BTH-0.3 achieves an 83.9% removal 

rate of tetracycline hydrochloride within 60 min irradiation under simulated sunlight, surpassing the 77.3% achieved by 

TH-2 loaded with only TiO 2 and the 62% achieved by pure Bi 2 O 3 . Furthermore, BTH-0.3 exhibits outstanding photocatalytic 

performance across varying solution pH levels and diverse water matrices. Moreover, consistent tetracycline hydrochloride 

removal rates were observed over four consecutive degradation cycles, demonstrating its excellent reusability. This research 

off ers a promising approach with practical potential for addressing water pollution challenges via photocatalytic technology. 

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