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In relation to this article, we declare that there is no conflict of interest.
Publication history
Received May 1, 2025
Revised August 9, 2025
Accepted August 16, 2025
Available online December 25, 2025
articles This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
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Most Cited

Effects of P/Na/Fe in Simulated Waste on Agglomeration and Defluidization During Fluidized Bed Incineration

Department of Civil and Environmental Engineering, National University of Kaohsiung,
cllin0407@nuk.edu.tw
Korean Journal of Chemical Engineering, December 2025, 42(14), 3555-3567(13)
https://doi.org/10.1007/s11814-025-00546-6

Abstract

To clarify the influence of the coexistence of Na, P, and Fe on agglomeration and defluidization, they were added to simulated

waste, and the operating parameters changed. Furthermore, P/Na, Fe/Na and P/Na/Fe:Na ratios are altered during the

experiment. Increasing the P/Na ratio gradually prolongs the time to agglomeration and defluidization, suggesting that the

presence of P suppresses agglomeration. Furthermore, increasing the Fe/Na ratio leads to a downward trend in the time

required for agglomeration and defluidization. Hence, the presence of Fe appears to increase the probability of agglomeration

and shorten the time required for agglomeration and defluidization. In the presence of all three elements, a P/Fe/Na ratio of

0.1/1/1 yields the shortest time for agglomeration and defluidization, suggesting that this condition is highly susceptible to

agglomeration. When the P/Fe/Na ratio is 0.6/5/1, the time to agglomeration and defluidization is the longest. By simultaneously

comparing the results from different P/Na and Fe/Na ratios, although the presence of Fe promotes agglomeration and

defluidization, the effect of P is greater than that of Fe. Hence, the coexistence of Na, P, and Fe results in a longer time for

agglomeration and defluidization when compared to that in the sole presence of Na.

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