ISSN: 0256-1115 (print version) ISSN: 1975-7220 (electronic version)
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In relation to this article, we declare that there is no conflict of interest.
Publication history
Received January 15, 2025
Revised March 15, 2025
Accepted March 25, 2025
Available online December 25, 2025
articles This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
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Advances in Anode Porous Transport Layer: Structural Design and Coating Strategy for Efficient Proton Exchange Membrane Water Electrolyzer

Center for Hydrogen and Fuel Cells, Korea Institute of Science and Technology (KIST) 1School of Integrative Engineering, Chung-Ang University 2Division of Energy and Environment Technology, KIST School, University of Science and Technology (UST) 3Green School, Korea University
sookilkim@cau.ac.kr
Korean Journal of Chemical Engineering, December 2025, 42(14), 3365-3378(14)
https://doi.org/10.1007/s11814-025-00455-8

Abstract

The anode porous transport layer (PTL) is crucial in proton exchange membrane water electrolyzers (PEMWEs), facilitating

efficient mass transport, electron conduction, and heat dissipation. This paper reviews advancements in PTL structural

design and coating strategies, emphasizing their impact on cell performance, durability, and cost-effectiveness. The acid

resistance of Ti-based PTLs has led to their widespread adoption; nonetheless, challenges such as increased ohmic resistance

and catalyst delamination caused by oxidation to TiO2

remain. A comprehensive investigation into the relationship

between PTL pore structure and PEMWE performance has yielded significant advancements, including gradient porosity

design, optimized pore structures, as well as thin and planar PTLs. Furthermore, anti-corrosion coatings, predominantly

comprising precious metal layers such as Pt and Ir, have enhanced durability and performance. However, high costs pose

significant constraints, prompting the exploration of non-precious material alternatives, including Nb, Ti, and Ta. In addition,

the emergence of porous transport electrodes has facilitated cost-effective, high-performance PEMWE systems by integrating

the dual-functional roles of catalytic activity and corrosion prevention. This paper provides key insights into designing

cost-effective and high-performance PTLs to support the future hydrogen economy.

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