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ISOMERIZATION OF 1-HEXENE CATALYZED OVER POLYMER-SUPPORTED RuCl2(PPh3)3
Korean Journal of Chemical Engineering, July 1991, 8(3), 183-187(5), 10.1007/BF02706681
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Abstract
Polymer-supported ruthenium catalyst was prepared by anchoring dichlorotris(triphenylphosphine)ruthenium, RuCl2(PPh3)3, onto the phosphinated polystyrene bead. The polymer-supported RuCl2(PPh3)3 could be reused several times with only small loss of catalytic activity in the isomerization of 1-hexene. The activity rather increased during the few initial runs. In both homogeneous and heterogenized catalysts, and induction period was required to initiate the isomerization. The catalyst efficiency was promoted in the mixture of good swelling solvent and potent hydrogen donor. Upon heterogenizing, the activity was reduced by a factor of 2.0-8.2.
References
Grubbs RH, Chemtech., 7, 512 (1977)
Hodge P, Sherrington DC, "Polymer-supported Reactions in Organic Synthesis," Wiley, Chichester (1980)
Hartley FR, "Supported Metal Complexes," Reidel, Dordrecht (1985)
Strathdee GZ, Given R, Can. J. Chem., 52, 3000 (1974)
Zoran A, Sasson Y, J. Org. Chem., 46, 255 (1981)
Tamborski C, Ford FE, Lehn WL, Moore GL, Soloski EJ, J. Org. Chem., 27, 619 (1962)
Strual A, Dolimpio P, Bonivents M, Pina P, Graziani M, J. Mol. Catal., 2, 179 (1976)
Sherman EO, Olson M, J. Org. Chem., 172, 13 (1979)
DeMunck NA, Verbruggen MW, DeLeur JE, Scholten JJF, J. Mol. Catal., 11, 331 (1981)
D'Aniello MJ, Barefield EK, J. Am. Chem. Soc., 100, 1474 (1978)
Hartley FR, Vezey PN, Adv. Org. Chem., 15, 189 (1977)
Levenspiel O, "Chemical Reaction Engineering," 2nd ed., Wiley, New York (1972)
Masters C, "Homogeneous Transition-Metal Catalysis," Chapman and Hall, New York (1981)
Hodge P, Sherrington DC, "Polymer-supported Reactions in Organic Synthesis," Wiley, Chichester (1980)
Hartley FR, "Supported Metal Complexes," Reidel, Dordrecht (1985)
Strathdee GZ, Given R, Can. J. Chem., 52, 3000 (1974)
Zoran A, Sasson Y, J. Org. Chem., 46, 255 (1981)
Tamborski C, Ford FE, Lehn WL, Moore GL, Soloski EJ, J. Org. Chem., 27, 619 (1962)
Strual A, Dolimpio P, Bonivents M, Pina P, Graziani M, J. Mol. Catal., 2, 179 (1976)
Sherman EO, Olson M, J. Org. Chem., 172, 13 (1979)
DeMunck NA, Verbruggen MW, DeLeur JE, Scholten JJF, J. Mol. Catal., 11, 331 (1981)
D'Aniello MJ, Barefield EK, J. Am. Chem. Soc., 100, 1474 (1978)
Hartley FR, Vezey PN, Adv. Org. Chem., 15, 189 (1977)
Levenspiel O, "Chemical Reaction Engineering," 2nd ed., Wiley, New York (1972)
Masters C, "Homogeneous Transition-Metal Catalysis," Chapman and Hall, New York (1981)
