ISSN: 0256-1115 (print version) ISSN: 1975-7220 (electronic version)
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English
Conflict of Interest
In relation to this article, we declare that there is no conflict of interest.
Publication history
Received January 19, 2026
Revised February 9, 2026
Accepted February 23, 2026
Available online May 25, 2026
articles This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
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Current Status and Future Directions of Anode Materials for SulfideBased All-Solid-State Batteries

Department of Chemical and Biomolecular Engineering, Yonsei University 1Department of Mechanical Engineering, Stanford University
Korean Journal of Chemical Engineering, May 2026, 43(6), 1521-1533(13)
https://doi.org/10.1007/s11814-026-00687-2

Abstract

Sulfide-based all-solid-state batteries (ASSBs) are regarded as next-generation high-safety, high-energy-density storage systems owing to the high ionic conductivity of sulfide-based solid-state electrolytes (SSEs), room-temperature processability, and intimate electrode–electrolyte contact. However, under practical operating conditions, performance degradation originating from anode-related instabilities remains a critical bottleneck. In particular, at the anode, the combination of low operating potential and large deformation induces interfacial reactions, contact evolution, and transport heterogeneity, resulting in their mutual amplification. Despite growing interest, studies that systematically synthesize anode-driven degradation in sulfide-based ASSBs from an electro-chemo-mechanical coupling perspective remain relatively limited. 

Accordingly, this review focuses on representative anode configurations, including Li metal, Si-based, and anode-free systems, and analyzes anode-induced degradation mechanisms in sulfide-based ASSBs within an electro-chemo-mechanical coupling framework. Finally, remaining challenges and future research directions toward anode-centric designs that precisely regulate interfacial chemistry, mechanical behavior, and Li+  transport are discussed.

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