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- Conflict of Interest
- In relation to this article, we declare that there is no conflict of interest.
- Publication history
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Received June 4, 2025
Revised November 27, 2025
Accepted December 28, 2025
Available online April 25, 2026
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This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
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Char Contribution as Heterogeneous Reaction To NO Reduction During Rice Husk Reburning in a Drop Tube Furnace
https://doi.org/10.1007/s11814-025-00639-2
Abstract
Biomass reburning has emerged as a promising method for reducing nitrogen oxide (NO) emissions. However, a comprehensive
understanding of reburning reactions using biomass remains limited. In particular, the char contribution to NO
reduction requires further clarifi cation, especially when using rice husk. This study investigates the contribution of rice
husk char to NO reduction during the reburning process in a drop-tube furnace. The eff ects of reaction temperature, NO
concentration, and equivalence ratio on the contribution of the homogeneous and heterogeneous reactions were analyzed.
Results showed that increasing the reburning temperature enhanced the heterogeneous reaction by promoting CO release
from the char surface, thereby increasing the char’s contribution to the overall reburning reaction. As the initial NO concentration
increased, NO reduction increased for both rice husk and its char; however, due to the limited amount of fuel
for reburning reactions, the rate of increase in NO reduction decreased. The homogeneous reaction decreased above a
certain equivalence ratio because oxygen limitation reduced the conversion of intermediate species into N 2 . In contrast,
the char reaction increased and eventually reached saturation with an increasing equivalence ratio, further enhancing char
contribution. These fi ndings provide valuable insights for optimizing biomass reburning systems, particularly by clarifying
the distinct role and operational dependencies of heterogeneous char-NO reactions.

