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In relation to this article, we declare that there is no conflict of interest.
Publication history
Received July 30, 2025
Revised November 13, 2025
Accepted December 28, 2025
Available online March 25, 2026
articles This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
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Structural and Electrochemical Optimization of Platinum-Saving Pt-CoNiO/C Catalysts Synthesized Via Green Methods for HighPerformance PEM Fuel Cells

Graduate School of Natural and Applied Sciences , Siirt University 1Department of Chemical Engineering, Faculty of Engineering , Siirt University 2Vocational School of Health Services , Harran University 3Department of Chemical Engineering, Faculty of Chemical and Metallurgical Engineering , İstanbul Technical University 4Faculty of Health Sciences, Department of Occupational Health and Safety , Siirt University
aekinci@siirt.edu.tr
Korean Journal of Chemical Engineering, March 2026, 43(4), 1085-1101(17)
https://doi.org/

Abstract

 This study evaluates the eff ectiveness of Pt-CoO/C, Pt-NiO/C, and Pt-CoNiO/C catalysts in PEM fuel cells, highlighting 

their interactions and synergistic eff ects on morphology, power density, current density, and electrochemical properties. 

The current study focuses on examining the structural and morphological characteristics of the catalysts using analytical

techniques such as TEM, XRD, and SEM-EDX. Pt-CoNiO/C outperforms conventional catalysts by demonstrating 

reduced ohmic and mass transport losses attributed to the synergistic eff ects of Pt, Co, and Ni, which favor electron 

dispersion and facilitate effi cient charge transfer. Pt-CoNiO/C has an electrochemical surface area (ECSA) of 141 m 2

 /g Pt , and its highest current density is 182 mA/cm 2. Its highest power density is 137 mW/cm 2. The performance of the catalyst 

improves with temperature, with Pt-CoNiO/C achieving the best rating at 70 °C. The results show that Pt-CoNiO/C can 

be used instead of Pt/C catalysts because it uses less platinum and still works well in PEM fuel cell applications. 

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