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In relation to this article, we declare that there is no conflict of interest.
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Accepted March 28, 2025
Available online June 25, 2025
articles This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
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Recent Progress of Materials Design and Engineering of Aqueous Metal-Air Batteries

Department of Advanced Materials Engineering , Keimyung University , 1095 Dalgubeol-daero, Dalseo-gu , Daegu 42601 , Republic of Korea 1Department of Chemical Engineering , Changwon National University , Changwon , Gyeongsangnam-do 51140 , Republic of Korea
Korean Journal of Chemical Engineering, June 2025, 42(7), 1491-1505(15)
https://doi.org/10.1007/s11814-025-00456-7

Abstract

Aqueous metal-air batteries have received great attention as possible candidates for environmentally sustainable energy

storage systems (ESS) based on their high energy density, high safety and low cost. Particularly, a variety of aqueous metalair

batteries have been studied for practical application. However, there are limitations arising from the intrinsic properties

of their components and battery designs. To address these drawbacks, a wide range of materials have been developed as

promising components for next-generation aqueous metal-air batteries. This review focuses on recent progress in materials

design and engineering of aqueous metal-air batteries including Zn–, Al–, Mg– and Fe–air batteries, which highlights the

development of novel materials and fabrication of innovative battery systems based on the metal anode, air cathode, aqueous

electrolyte and electrocatalysts. Furthermore, fl exible and fl ow batteries are intensively introduced as advanced aqueous

metal-air batteries for future electronic devices. On the basis of these viewpoints, this review provides a future direction for

the commercialization of aqueous metal-air batteries.

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