ISSN: 0256-1115 (print version) ISSN: 1975-7220 (electronic version)
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In relation to this article, we declare that there is no conflict of interest.
Publication history
Received January 23, 2025
Accepted April 20, 2025
Available online June 25, 2025
articles This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
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Bio-inspired Fabrication of SLS-MWCNTs Multifunctional Composite Membrane with Bionic Coating for Effi cient Separation of Complex Oily Wastewater

College of Chemistry and Chemical Engineering , Southwest Petroleum University , 8 Xindu Avenue, Xindu District , Chengdu 610500 , Sichuan , China 1Key Laboratory of Applied Chemistry for Oil and Gas Fields , 8 Xindu Avenue, Xindu District , Chengdu 610500 , Sichuan , China
Korean Journal of Chemical Engineering, June 2025, 42(6), 1317-1330(14)
https://doi.org/10.1007/s11814-025-00471-8

Abstract

Industrial development has led to the generation of large amounts of oily wastewater, which poses signifi cant threats to both

environment and human health. These wastewater streams often contain various pollutants, such as organic dyes and heavy

metal ions, creating an urgent need for multifunctional materials capable of effi ciently separating these contaminants. In this

study, we deposited sodium lignosulfonate (SLS)-modifi ed multi-walled carbon nanotubes (MWCNTs) onto polyvinylidene

fl uoride (PVDF) polymer membranes by vacuum fi ltration. Subsequently, a hydrophilic bio-inspired coating, consisting of

pyrogallic acid (PG) and silane-coupling agent (KH550), was deposited on the membrane surface. The resulting composite

membrane exhibited exceptional superhydrophilicity and underwater superoleophobicity. This membrane demonstrated high

effi ciency in separating various oil–water emulsions, with a separation effi ciency reaching 99% and a stable separation fl ux

maintained above 350 L m

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