Articles & Issues
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- Conflict of Interest
- In relation to this article, we declare that there is no conflict of interest.
- Publication history
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Received May 29, 2024
Accepted August 22, 2024
Available online April 25, 2025
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This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
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Synthesis and Property Control of Bead-Shaped Silica Adsorbents for Rhodamine B Dye Adsorption
https://doi.org/10.1007/s11814-024-00266-3
Abstract
In this study, we synthesized Bead-Shaped Silica and evaluated its performance in adsorbing the dye Rhodamine B. The
Bead-Shaped Silica (BS) was synthesized without the use of harmful substances. The BS Adsorbent was synthesized using
silica powder and the eco-friendly biopolymer sodium alginate through the Egg box junction method. It was found that by
adjusting the molar ratio of silica to alginate during the manufacturing process, the specifi c surface area and pore size could
be controlled. The BS-2.5 sample exhibited the highest surface area and adsorption capacity due to the eff ective removal of
alginate during heat treatment. The pseudo-fi rst-order adsorption kinetic constants and eff ective diff usivity of the BS material
decreased with decreasing pore size, while the adsorption capacity increased. The adsorption behavior of Rhodamine
B was modeled using Langmuir and Freundlich isotherms. Based on calculations using these models, the BS-2.5 sample,
which had the largest surface area, showed the best performance. Additionally, in continuous fl ow system experiments, the
use of BS resulted in clean water production, whereas columns with silica powder experienced structural damage and dye
leakage due to severe pressure drops.

