Articles & Issues
- Language
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- Conflict of Interest
- In relation to this article, we declare that there is no conflict of interest.
- Publication history
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Received December 2, 2024
Accepted December 17, 2024
Available online March 25, 2025
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This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
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Effect of Surface Tension on Thermocapillary Convection-Driven Droplet Transport
https://doi.org/10.1007/s11814-024-00368-y
Abstract
The transport of microliter-scale droplets on solid surfaces is critical for various applications, including microfl uidics and
microengines. Recently, droplet manipulation strategy using thermocapillary convection has received attention due to its
precise and remote controllability. The mobility of liquid droplets in this method depends on several parameters, such as laser
power and the light absorption coeffi cient. Additionally, surface tension signifi cantly infl uences droplet movement although
its underlying mechanism remains unclear. In this study, we investigate the eff ect of surface tension on droplet movement
via thermocapillary convection. Aqueous dispersions of polypyrrole (PPy) nanoparticles (NPs), which absorb near-infrared
(NIR) light and convert it into heat, are employed as droplets. Upon NIR laser irradiation, the PPy droplets generate localized
heat, resulting in thermocapillary convection. The lubricated surface (LuS) is used as a substrate. Due to the mobile
lubricant layer, droplets are easy to move with low friction. Surface tension is modifi ed by adding a surfactant, and the
droplet movement speed increases with decreasing surface tension. Here, this phenomenon is investigating the parameters
acting to Marangoni force: contact line length and surface tension gradient. We confi rm that the Marangoni force, which
propels the droplet, is induced more eff ectively by low surface tension liquids. This study provides fundamental insights into
droplet behavior governed by wettability diff erences, advancing droplet manipulation techniques for diverse fl uidic systems.

