ISSN: 0256-1115 (print version) ISSN: 1975-7220 (electronic version)
Copyright © 2025 KICHE. All rights reserved

Articles & Issues

Language
English
Conflict of Interest
In relation to this article, we declare that there is no conflict of interest.
Publication history
Received September 15, 2025
Revised September 15, 2025
Accepted September 23, 2025
Available online December 25, 2025
articles This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
Copyright © KIChE. All rights reserved.

All issues

Ballistic Transport in Plasma Oxide Etching: A Realistic Universal Surface Reaction Model

School of Semiconductor and Chemical Engineering, Jeonbuk National University 1Kyungwon Tech. Co. Ltd.
yeonhoim@jbnu.ac.kr
Korean Journal of Chemical Engineering, December 2025, 42(14), 3583-3597(15)
https://doi.org/10.1007/s11814-025-00571-5

Abstract

We propose a universal surface reaction model that incorporates neutral and ion transport mechanisms through a steadystate

passivation layer in high-aspect-ratio plasma oxide etching. This two-layer model effectively captures the concurrent

deposition and etching characteristics by explicitly accounting for neutral diffusion and ion scattering transport processes.

Detailed kinetic models for deposition and etching are developed to closely reflect the transport mechanisms in a steady-state

passivation layer (SSPL), and their validity is supported by sensitivity analyses of key parameters against experimental data.

Consequently, the proposed model provides a realistic description of plasma oxide etching behavior. Furthermore, by integrating

this model with a well-established three-dimensional ballistic transport model in high-aspect-ratio (HAR) structures,

we offer valuable insights into previously unexplored aspects of the HAR etching process.

The Korean Institute of Chemical Engineers. F5,119, Anam-ro, Seongbuk-gu, Seoul, Republic of Korea
TEL. No. +82-2-458-3078FAX No. +82-507-804-0669E-mail : kiche@kiche.or.kr

Copyright (C) KICHE.all rights reserved.

- Korean Journal of Chemical Engineering 상단으로