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In relation to this article, we declare that there is no conflict of interest.
Publication history
Received June 9, 2025
Accepted July 30, 2025
Available online November 25, 2025
articles This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
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Enhanced Photocurrent of Electrodeposited Copper Oxide Films Doped with Solution‑Processable Organic Cationic Dye as a Dopant

Department of Chemical Engineering, Pukyong National University 1Department of Smart Green Technology Engineering, Pukyong National University 2Department of Semiconductor Engineering, Division of Nanotechnology and Semiconductor Engineering, Pukyong National University
jiyoul_lee@pknu.ac.kr, eklee@pknu.ac.kr
Korean Journal of Chemical Engineering, November 2025, 42(13), 3285-3291(7)
https://doi.org/10.1007/s11814-025-00533-x

Abstract

Copper oxide (

Cu2O) is a promising p-type semiconductor due to its low cost, environmental stability. However, increasing

the crystallinity of Cu2O

thin film has been a challenge. In this study, high-quality Cu2O

thin film is successfully fabricated

via electrodeposition method under ambient conditions, eliminating the need for vacuum environment. Finally, the organic

cationic dye, crystal violet (CV), is doped onto Cu2O

in two forms (thermal deposition and solution process). Both doping

methods involve converting the dopants from colored to leuco form. After doping, the contact between Cu2O

and the

electrode transitions from a Schottky contact to Ohmic-like and Ohmic contact. And it induces enhanced current in the

semiconductor Cu2O

under light stimulation for photosensor applications through light absorption and photon generation.

Through morphological analysis of different distribution patterns of dopants and optical characterization, solution reduced

CV-doped photosensor emerges as the photosensor exhibiting the highest optical performance. This technology suggests the

potential for cheap and effective photosensor fabrication and the device to be utilized in various optical applications with

good ohmic contact.

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