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In relation to this article, we declare that there is no conflict of interest.
Publication history
Received April 23, 2024
Accepted September 5, 2024
articles This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
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Improving Quantum Dot Stability Against Heat and Moisture with Cyclic Olefi n Copolymer Matrix

Korean Journal of Chemical Engineering, December 2024, 41(13), 3461-3468(8)
https://doi.org/10.1007/s11814-024-00278-z

Abstract

Quantum dots (QDs) are widely studied for their superior optical properties. However, maintaining their stability requires

eff ective protection against heat and moisture. This research aims to enhance the stability of QDs by embedding them in cyclic

olefi n copolymer (COC). Our fi ndings show that nanocomposites containing green- and red-emitting QDs in COC exhibited

enhanced transparency and dispersion when compared to those using other common polymers, such as polydimethylsiloxane

(PDMS) and poly(methyl methacrylate) (PMMA). Stability test under harsh conditions (85 °C and 85% relative humidity)

confi rmed the robustness of the QDs within the COC matrix compared to the PDMS and PMMA matrices. In addition, a

white-light-emitting diode (LED) device was successfully fabricated by integrating a blend of green- and red-emitting QDs

in COC-based nanocomposites atop a blue LED chip. This setup demonstrated potential for use in light-emitting devices

that demand high luminous effi ciency and transparency, even under extreme conditions. The study highlights the potential

of COC as an alternative to traditional polymers, enhancing the performance and durability in display technologies.


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