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Received March 31, 2022
Accepted July 29, 2022
articles This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
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An effective and smart corrosion inhibitor in acidic environment: Experimental & theoretical studies

Engineering Laboratory of Organometallic, Molecular Materials, and Environment, Faculty of Sciences, University Sidi Mohamed Ben Abdellah, Fez, Morocco 1School of Chemical Engineering, Yeungnam University, Gyeongsan 38541, Korea 2Centre d’élaboration de Matériaux et d’études Structurales, CEMES-CNRS, UPR 8011, F-31055 Toulouse, France 3Applied Chemistry-Physic Team, Faculty of Sciences, University of Ibn Zohr, Agadir, Morocco 4Math. and Sci. Edu., Sivas Cumhuriyet University, Math, 58140, Sivas, Turkey
salimrajae@gmail.com
Korean Journal of Chemical Engineering, January 2023, 40(1), 235-247(13), 10.1007/s11814-022-1246-5
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Abstract

The application of corrosion inhibitors is the best way to protect metals from degradation. Therefore, the P-anisidine molecule was investigated as a corrosion inhibitor for mild steel in a 1M HCl medium. This study used different methods, such as electrochemical impedance spectroscopy, polarization potentiodynamic curves, scanning electron microscopy, and theoretical method. The addition of this molecule to the aggressive medium achieved inhibition of 81% at a concentration of 10-3M. The potentiodynamic polarization curves reveal a mixed type character (anodic and cathodic) and adsorb on the metal surface according to Langmuir adsorption isotherm. This adsorption was also proved by scanning electron microscopy proving the presence of a protective layer on the steel surface used. The theoretical results confirmed the experimental part and showed that P-anisidine adsorbed parallel onto the steel surface covering a large surface area.

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