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Received November 19, 2020
Accepted December 17, 2020
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Two component phase equilibria for the 3-methoxy-3-methyl-1-butanol and 1-methoxy-2-methyl-2-propanol in supercritical carbon dioxide
Department of Chemical and Biomolecular Engineering, Chonnam National University, Yeosu, Jeonnam 59626, Korea
Korean Journal of Chemical Engineering, March 2021, 38(3), 610-616(7), 10.1007/s11814-020-0733-9
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Abstract
Two component mixtures, 3-methoxy-3-methyl-1-butanol (MMB)+carbon dioxide and 1-methoxy-2- methyl-2-propanol (MMP)+carbon dioxide, were investigated at 313.2, 333.2, 353.2, 373.2 and 393.2 K and at 4.29 to 20.95MPa to get phase equilibrium data. The phase separation of vapor+liquid behavior for the MMB and MMP plays a momentous function as the organic solvent in a diversity of industrial processes. The two MMB+carbon dioxide and MMP+carbon dioxide components have mixture critical curves that have maxima in the p-T plot between the Tc (critical temperatures) of MMB and carbon dioxide or MMP and carbon dioxide. The two component systems of MMB+ carbon dioxide and MMP+carbon dioxide mixture display type-I in simplest behavior. The measured results for the two component mixtures, MMB+carbon dioxide and MMP+carbon dioxide, are modelled with a general cubic equation of state, the Peng-Robinson, containing the kij, ηij adjustable factor.
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References
https://www.sigmaaldrich.com/catalog/product/aldrich/408069?lang=ko®ion=KR.
https://www.scbt.com/ko/p/3-methoxy-3-methyl-1-butanol-56539-66-3.
https://hpvchemicals.oecd.org/UI/handler.axd?id=D255FC4A-C80F-4A42-8D1D-C641397B0427.
Kiran E, J. Supercrit. Fluids, 47(3), 466 (2009)
Gregorowicz J, Fermeglia M, Soave G, Kikic I, Chem. Eng. Sci., 46, 1427 (1991)
Choo YS, Yeo WH, Byun HS, J. CO2 Utilization, 31, 215 (2019)
Byun HS, Kim CR, Yoon SD, J. Supercrit. Fluids, 120, 226 (2017)
Tomasko DL, Li HB, Liu DH, Han XM, Wingert MJ, Lee LJ, Koelling KW, Ind. Eng. Chem. Res., 42(25), 6431 (2003)
https://www.kuraray.com/products/solfit.
Wilson GM, VonNiederhausern DM, Giles NF, J. Chem. Eng. Data, 47(4), 761 (2002)
Rindfleisch F, DiNoia TP, McHugh MA, J. Phys. Chem., 100(38), 15581 (1996)
Jeong JD, Byun HS, Korean Chem. Eng. Res., 57(6), 826 (2019)
Yim JH, Choo YS, Byun HS, J. Chem. Thermodyn., 130, 140 (2019)
Hsieh CM, Windmann T, Vrabec J, J. Chem. Eng. Data, 58(12), 3420 (2013)
Secuianu C, Feroiu V, Geana D, J. Chem. Eng. Data, 53(10), 2444 (2008)
Byun HS, Kwak C, Korean J. Chem. Eng., 19(6), 1007 (2002)
Peng DY, Robinson DE, Ind. Eng. Chem. Fundam., 15, 59 (1976)
Poling BE, Prausnitz JM, O’Connell JP, The properties of liquids and gases, 5th Ed., McGraw-Hill, New York (2001).
Cho SH, Lee BS, Byun HS, J. CO2 Utilization, 25, 39 (2018)
Lee BS, Lee JK, Bong JH, Byun HS, Fluid Phase Equilib., 462, 1 (2018)
Chirico RD, Frenkel M, Diky VV, Marsh KN, Wilhoit RC, J. Chem. Eng. Data, 48(5), 1344 (2003)
Yoon SD, Byun HS, J. Chem. Thermodyn., 71, 91 (2014)
Scott RL, van Konynenburg PB, Discuss. Faraday Soc., 49, 87 (1970)
McHugh MA, Krukonis VJ, Supercritical fluid extraction, 2nd Ed., Butterworth-Heinemann: Stoneham (1994).
https://www.fishersci.com/shop/products/3-methoxy-3-methyl-1-butanol-98/AAL15953 AE#?keyword =3-Methoxy-3-methyl-1-butanol.
https://www.fishersci.com/shop/products/1-methoxy-2-methyl-2-propanol-98-1/ AAL2035114.
https://www.scbt.com/ko/p/3-methoxy-3-methyl-1-butanol-56539-66-3.
https://hpvchemicals.oecd.org/UI/handler.axd?id=D255FC4A-C80F-4A42-8D1D-C641397B0427.
Kiran E, J. Supercrit. Fluids, 47(3), 466 (2009)
Gregorowicz J, Fermeglia M, Soave G, Kikic I, Chem. Eng. Sci., 46, 1427 (1991)
Choo YS, Yeo WH, Byun HS, J. CO2 Utilization, 31, 215 (2019)
Byun HS, Kim CR, Yoon SD, J. Supercrit. Fluids, 120, 226 (2017)
Tomasko DL, Li HB, Liu DH, Han XM, Wingert MJ, Lee LJ, Koelling KW, Ind. Eng. Chem. Res., 42(25), 6431 (2003)
https://www.kuraray.com/products/solfit.
Wilson GM, VonNiederhausern DM, Giles NF, J. Chem. Eng. Data, 47(4), 761 (2002)
Rindfleisch F, DiNoia TP, McHugh MA, J. Phys. Chem., 100(38), 15581 (1996)
Jeong JD, Byun HS, Korean Chem. Eng. Res., 57(6), 826 (2019)
Yim JH, Choo YS, Byun HS, J. Chem. Thermodyn., 130, 140 (2019)
Hsieh CM, Windmann T, Vrabec J, J. Chem. Eng. Data, 58(12), 3420 (2013)
Secuianu C, Feroiu V, Geana D, J. Chem. Eng. Data, 53(10), 2444 (2008)
Byun HS, Kwak C, Korean J. Chem. Eng., 19(6), 1007 (2002)
Peng DY, Robinson DE, Ind. Eng. Chem. Fundam., 15, 59 (1976)
Poling BE, Prausnitz JM, O’Connell JP, The properties of liquids and gases, 5th Ed., McGraw-Hill, New York (2001).
Cho SH, Lee BS, Byun HS, J. CO2 Utilization, 25, 39 (2018)
Lee BS, Lee JK, Bong JH, Byun HS, Fluid Phase Equilib., 462, 1 (2018)
Chirico RD, Frenkel M, Diky VV, Marsh KN, Wilhoit RC, J. Chem. Eng. Data, 48(5), 1344 (2003)
Yoon SD, Byun HS, J. Chem. Thermodyn., 71, 91 (2014)
Scott RL, van Konynenburg PB, Discuss. Faraday Soc., 49, 87 (1970)
McHugh MA, Krukonis VJ, Supercritical fluid extraction, 2nd Ed., Butterworth-Heinemann: Stoneham (1994).
https://www.fishersci.com/shop/products/3-methoxy-3-methyl-1-butanol-98/AAL15953 AE#?keyword =3-Methoxy-3-methyl-1-butanol.
https://www.fishersci.com/shop/products/1-methoxy-2-methyl-2-propanol-98-1/ AAL2035114.
