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Received October 20, 2017
Accepted January 11, 2018
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Photoreduction of CO2 into CH4 using Bi2S3-TiO2 double-layered dense films
Department of Chemistry, College of Sciences, Yeungnam University, Gyeongsan, Gyeongbuk 38541, Korea 1School of Chemical Engineering, Yeungnam University, Gyeongsan, Gyeongbuk 38541, Korea 2Institute for Advanced Engineering, 175-28, Goan-ro 51beon-gil, Baegam-Myyeon, Cheoin-gu, Yongin-si, Gyeonggi 17180, Korea 3Korea Electric Power Corporation Research Institute, 105 Munji-ro, Yuseong-gu, Daejeon 34056, Korea
Korean Journal of Chemical Engineering, May 2018, 35(5), 1089-1098(10), 10.1007/s11814-018-0007-y
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Abstract
Nano-sized bismuth sulfide (Bi2S3) and titanium dioxide (TiO2) with the orthorhombic and anatase tetragonal structures, respectively, were synthesized for application as catalysts for the reduction of carbon dioxide (CO2) to methane (CH4). Four double-layered dense films were fabricated with different coating sequences.TiO2 (bottom layer)/Bi2S3 (top layer), Bi2S3/TiO2, TiO2/Bi2S3 : TiO2 (1 : 1) mix, and Bi2S3 : TiO2 (1 : 1) mix/Bi2S3 : TiO2 (1 : 1) mix.and applied to the photoreduction of CO2 to CH4; the catalytic activity of the fabricated films was compared to that of the pure TiO2/TiO2 and Bi2S3/Bi2S3 doubled-layered films. The TiO2/Bi2S3 double-layered film exhibited superior photocatalytic behavior, and higher CH4 production was obtained with the TiO2/Bi2S3 double-layered film than with the other films. A model of the mechanism underlying the enhanced photoactivity of the TiO2/Bi2S3 double-layered film was proposed, and it was attributed in effective charge separation.
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References
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Senboku H, Katayama A, Curr. Opinion Green Sustain. Chem., 3, 50 (2017)
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Li X, Wen J, Low J, Fang Y, Yu J, Sci. China Mater., 57, 70 (2014)
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Lee JH, Kim SI, Park SM, Kang M, Ceram. Int., 43, 1768 (2017)
Meng X, Yu Q, Liu G, Shi L, Zhao G, Liu H, Li P, Chang K, Kako T, Ye J, Nano Energy, 34, 524 (2017)
Reddy CV, Shim J, Cho M, J. Phys. Chem. Solids, 103, 209 (2017)
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Sun Y, Li G, Xu J, Sun Z, Mater. Lett., 174, 238 (2016)
Li H, Yang J, Zhang J, Zhou M, Roy. Soc. Chem., 2, 6258 (2012)
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Wu W, Wu Z, Yu T, Jiang C, Kim WS, Sci. Technol. Adv. Mater., 16, 023501 (2015)
Im Y, Kang S, Kim KM, Ju T, Han GB, Park NK, Lee TJ, Kang M, Int. J. Photoenergy, 2013, 452542 (2013)
Kumar S, Sharma S, Sood S, Umar A, Kansal SK, Ceram. Int., 42, 17551 (2016)
Deshpande MP, Sakariya PN, Bhatt SV, Garg N, Patel K, Chaki SH, Mater. Sci. Semicond. Process, 21, 108 (2014)
Chaturvedi A, Joshi MP, Mondal P, Sinha AK, Srivastava AK, Appl. Surf. Sci., 396, 303 (2017)
Park M, Kwak BS, Jo SW, Kang M, Energy Conv. Manag., 103, 431 (2015)
Wang J, Xia Y, Dong Y, Chen RS, Xiang L, Komarneni S, Appl. Catal. B: Environ., 192, 8 (2016)
Panesar DK, Francis J, Constr. Build. Mater., 52, 52 (2014)
Khalfaoui M, Knani S, Hachicha MA, Ben Lamine A, J. Colloid Interface Sci., 263(2), 350 (2003)
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Kubacka A, Munoz-Batista MJ, Ferrer M, Fernandez-Garcia M, Appl. Catal. B: Environ., 140-141, 680 (2013)
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Yao Y, Goodman DW, J. Mol. Catal. A-Chem., 383-384, 239 (2014)
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Singhal N, Kumar U, Mol. Catal., 439, 91 (2017)
Yu H, Huang J, Zhang H, Zhao Q, Zhong X, Nanotechnology, 25, 215702 (2014)
Kato T, Hakari Y, Ikeda S, Jia Q, Iwase A, Kudo A, J. Phys. Chem. Lett., 6, 1042 (2015)
He H, Berglund SP, Xiao P, Chemelewski WD, Zhang Y, Mullins CB, J. Mater. Chem. A, 1, 12826 (2013)
Farhangi N, Chowdhury RR, Medina-Gonzalez Y, Ray MB, Charpentier PA, Appl. Catal. B: Environ., 110, 25 (2011)
Lee JH, Lee H, Kang M, Mater. Lett., 178, 316 (2016)
Kalanur SS, Hwang YJ, Joo OS, J. Colloid Interface Sci., 402, 94 (2013)
