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Received August 12, 2016
Accepted December 21, 2016
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Isotherm, kinetic and thermodynamic studies for Th(IV) sorption by amino group-functionalized titanosilicate from aqueous solutions
Nuclear Fuel Cycle Research School, Nuclear Science and Technology Research Institute, AEOI, P. O. Box 14893-836, Tehran, Iran 1School of Chemical Engineering, College of Engineering, University of Tehran, P. O. Box 11365-4563, Tehran, Iran
m.karimi407@alumni.ut.ac.ir, mohammadkarimi407@gmail.com
Korean Journal of Chemical Engineering, April 2017, 34(4), 1159-1169(11)
https://doi.org/10.1007/s11814-016-0357-2
https://doi.org/10.1007/s11814-016-0357-2
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Abstract
The 3-aminopropyltriethoxysilane-modified titanosilicate was prepared as an alternative for developing efficient adsorbents of heavy metals. The obtained material was characterized by X-ray diffraction analysis, infrared spectroscopy, textural analysis, and scanning electron microscopy. Adsorption of thorium from aqueous solutions was investigated by adsorption isotherms, kinetic and thermodynamic studies. The isothermal data were found to be correlated with the Langmuir model. The maximum sorption capacity of Th(IV) was 83.4mg g-1. The experimental data show that the external diffusion and intra-particular diffusion are significant in the sorption of thorium. The thermodynamic parameters indicated that the sorption process was physisorption, endothermic and spontaneous.
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Son BC, Park K, Song SH, Yoo YJ, Korean J. Chem. Eng., 21(6), 1168 (2004)
Hahm HC, Lee DW, Hong WH, Lee TY, Lee CH, Korean J. Chem. Eng., 20(4), 716 (2003)
Nasab ME, Sam A, Milani AA, Hydrometallurgy, 106, 141 (2011)
Soylak M, Erdogan ND, J. Hazard. Mater., 137(2), 1035 (2006)
Matlock MM, Howerton BS, Atwood DA, Water Res., 36, 4757 (2002)
Prabhakar S, Misra BM, Roy SB, Meghal AM, Mukherjee TK, Sep. Sci. Technol., 29(8), 1001 (1994)
Abu Qdais H, Moussa H, Desalination, 164(2), 105 (2004)
Schlichter B, Mavrov V, Erwe T, Chmiel H, J. Membr. Sci., 232(1-2), 99 (2004)
Fillipi BR, Scamehorn JF, Christian SD, Taylor RW, J. Membr. Sci., 145(1), 27 (1998)
Canizares P, Perez A, Camarillo R, Desalination, 144(1-3), 279 (2002)
El-Naggar IM, Hebash KA, Sheneshen ES, Abdel-Galil EA, ICAIJ, 9, 1 (2014)
El-Naggar IM, Sheneshen ES, Abdel-Galil EA, Desalination Water Treatment, 1, 1 (2014)
Aydin FA, Soylak M, J. Hazard. Mater., 173(1-3), 669 (2010)
El Samrani AG, Lartiges BS, Villieras F, Water Res., 42, 951 (2008)
Rule P, Balasubramanian K, Gonte RR, J. Environ. Radioact, 136, 22 (2014)
Guerra DL, Viana RR, Airoldi C, J. Braz. Chem. Soc., 20, 1164 (2009)
Metaxas M, Kasselouri-Rigopoulou V, Galiatsatou P, Konstantopoulou C, Oikonomou D, J. Hazard. Mater., 97(1-3), 71 (2003)
Hongxia Z, Zheng D, Zuyi T, Colloids Surf. A: Physicochem. Eng. Asp., 278, 46 (2006)
Chen C, Wang X, Appl. Radiat Isot., 65, 155 (2007)
Zhao DL, Feng SJ, Chen CL, Chen SH, Xu D, Appl. Clay Sci., 41, 17 (2007)
Nilchi A, Dehaghan TS, Garmarodi SR, Desalination, 32, 67 (2013)
Kazy SK, D'Souza SF, Sar P, J. Hazard. Mater., 163(1), 65 (2009)
Bhainsa KC, D'Souza SF, J. Hazard. Mater., 165(1-3), 670 (2009)
Talip Z, Eral M, Hicsonmez U, J. Environ. Radioact, 100, 139 (2009)
Popa K, Pavel CC, Desalination, 293, 78 (2012)
Panda GC, Das SK, Guha AK, Colloids Surf. B: Biointerfaces, 62, 173 (2008)
Tanchuk B, Sawada JA, Kuznicki SM, AIChE J., 59, 12 (2013)
Marcal L, de Faria EH, Saltarelli M, Calefi PS, Nassar EJ, Ciuffi KJ, Trujillano R, Vicente MA, Korili SA, Gil A, Ind. Eng. Chem. Res., 50(1), 239 (2011)
Anbia M, Khosravi F, Dehghan R, J. Ultrafine Grained Nanostructured Mater., 49, 36 (2016)
Kostov-Kytin V, Mihailova B, Kalvachev Y, Tarassov M, Microporous Mesoporous Mater., 86, 223 (2005)
Saravanan R, Rani MP, Metal and Alloy Bonding: An Experimental Analysis-Charge Density in Metals and Alloys, Springer (2012).
Patterson A, Phys. Rev., 56, 978 (1939)
Dubinin MM, Characterisation of Porous Solids. London: The Society of Chemical Industry (1979).
Terzyk AP, Gauden PA, Kowalczyk P, Carbon, 40, 2879 (2002)
Rahman I, Jafarzadeh M, Sipaut C, Ceram. Int., 35, 1883 (2009)
McDonald AM, Chao GY, The Canadian Mineralogist, 42, 769 (2004)
Kostov-Kytin V, Mihailova B, Kalvachev Y, Microporous Mesoporous Mater., 86, 223 (2005)
Su LLF, Zhao X, J. Porous Mat., 13, 263 (2006)
Anbia M, Lashgari M, Chem. Eng. J., 150(2-3), 555 (2009)
Gupta VK, Gupta B, Rastogi A, Agarwal S, Nayak A, J. Hazard. Mater., 186(1), 891 (2011)
Gupta VK, Mittal A, Malviya A, Mittal J, J. Colloid Interface Sci., 355, 24 (2009)
Li YH, Luan Z, Xiao X, Zhou X, Xu C, Wu D, Wei B, Adsorpt. Sci. Technol., 21, 475 (2003)
Unuabonah EI, Adebowale KO, Olu-Owolabi BI, Yang LZ, Kong LX, Hydrometallurgy, 63, 1 (2008)
Huang YR, Li ZJ, Wang HF, Miao ZC, Liu JG, Appl. Chem. Ind., 38, 1093 (2009)
Abbasizadeh S, Keshtkar AR, Mousavian MA, Chem. Eng. J., 220, 161 (2013)
Ho YS, Mckay G, Water Air Soil Pollut., 158, 77 (2004)
Hao YM, Chen M, Hu ZB, J. Hazard. Mater., 184(1-3), 392 (2010)
Hameed BH, Mahmoud DK, Ahmad AL, J. Hazard. Mater., 158(1), 65 (2008)
Zheng H, Liu DH, Zheng Y, Liang SP, Liu Z, J. Hazard. Mater., 167(1-3), 141 (2009)
Zheng H, Wang Y, Zheng Y, Zhang HM, Liang SP, Long M, Chem. Eng. J., 143(1-3), 117 (2008)
Saltali K, Sari A, Aydin M, J. Hazard. Mater., 141(1), 258 (2007)
Saltalı K, Sarı A, Adsorpt. Sci. Technol., 24, 749 (2006)
Dubinin MM, Zaverina ED, Radushkevich LV, Zhurnal Fizicheskoi Khimii, 21, 1351 (1947)
Sag Y, Kutsal T, Biochem. Eng. J., 6, 145 (2000)
Trapnell BMW, Hayward DO, Trapnell, Chemisorption, Butterworth, London (1964).
