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Received July 5, 2016
Accepted February 2, 2017
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Adsorption of ibuprofen sodium salt onto Amberlite resin IRN-78:Kinetics, isotherm and thermodynamic investigations
1Materials, Environment and Energy Laboratory (UR14ES26), Science Faculty of Gafsa, University of Gafsa, Tunisia 2Science Faculty of Gafsa, 2112, Gafsa, University of Gafsa, Tunisia 3Physical Organic Chemistry Laboratory (UR11ES74), Science Faculty of Sfax, University of Sfax, Tunisia
Korean Journal of Chemical Engineering, April 2017, 34(4),
10.1007/s11814-017-0012-6
10.1007/s11814-017-0012-6
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Abstract
Amberlite resin IRN-78 was used for the adsorption of Ibuprofen sodium salt (IBP) from liquid phase. The effects of solvent, initial concentration, solution pH, temperature and contact time were investigated. Adsorption studies were carried out in water and in ethanol. It was found that the adsorption capacity was dependent on pH. The optimum pH range was between 6 and 10. The maximum adsorption capacities on the IRN-78 were 1.266 and 0.611 mmol/g for IBP in water and in ethanol, respectively. The equilibrium data of the adsorption of IBP onto IRN-78 fit well to the Langmuir model. The separation factor (RL) values were in the range of 0-1, indicating that the adsorption was favorable. The values of thermodynamic parameters including ΔG°, ΔH° and ΔS° demonstrated that the adsorption of IBP onto IRN-78 was spontaneous and endothermic within the temperature range of 288-308 K. The adsorption process was controlled by physical mechanism rather than chemical mechanism.
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References
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Cleuvers M, Toxicology Lett., 142, 185 (2003)
Madikizela LM, Chimuka L, J. Pharm. Biomed. Anal., 128, 210 (2016)
Li Y, Wuc B, Zhu G, Liu Y, Jern W, Appan A, Tan SK, Sci. Total Environ., 562, 604 (2016)
Luo Y, Guo W, Ngo HH, Nghiem LD, Hai FI, Zhang J, Liang S, Wan XC, Sci. Total Environ., 473-474, 619 (2014)
Daughton CG, Ternes TA, Environ. Health Perspect., 107, 907 (1999)
Ambuludi SL, Panizza M, Oturan N, Ozcan A, Oturan MA, Environ. Sci. Pollut. Res., 20, 2381 (2013)
Verlicchi P, Galletti A, Petrovic M, Barcelo D, J. Hydrology, 389, 416 (2010)
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Gupta VK, Ali I, Saini VK, J. Colloid Interface Sci., 315(1), 87 (2007)
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Comerton AM, Andrews RC, Bagley DM, Hao CY, J. Membr. Sci., 313(1-2), 323 (2008)
Rohricht M, Krisam J, Weise U, Kraus UR, During RA, Desalination, 250(3), 1025 (2010)
Reungoat J, Macova M, Escher BI, Carswell S, Mueller JF, Keller J, Water Res., 44, 625 (2010)
Joss A, Keller E, Alder A, Gobel A, McArdell C, Ternes T, Siegrist H, Water Res., 39, 3139 (2005)
Salgado R, Marques R, Noronha JP, Carvalho G, Oehmen A, Reis MAM, Environ. Sci. Pollut. Res., 19, 1818 (2012)
Dominguez JR, Gonzalez T, Palo P, Cuerda-Correa EM, Desalination, 269(1-3), 231 (2011)
Vulava VM, Cory WC, Murphey VL, Ulmer CZ, Sci. Total Environ., 565, 1063 (2016)
Guedidi H, Reinert L, Leveque JM, Soneda Y, Bellakhal N, Duclaux L, Carbon, 54, 432 (2013)
Sukul P, Lamshoft M, Zuhlke S, Spiteller M, Chemosphere, 73, 1344 (2008)
Cho HH, Huang H, Schwab K, Langmuir, 27(21), 12960 (2011)
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Singare PU, Kerentechnik, 79, 51 (2014)
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Sun J, Li X, Quan Y, Yin Y, Zheng S, Chemosphere, 136, 181 (2015)
Landry KA, Sun P, Huang CH, Boyer TH, Water Res., 68, 510 (2015)
Bauerlein PS, ter Laak TL, Hofman-Caris RCHM, de Voogt P, Droge STJ, Water Res., 46, 5009 (2012)
Shan Y, Song Y, Liu Y, Liu R, Du J, Zeng P, Environ. Earth Sci., 73, 4989 (2015)
Beltran G, Esteve-Zarzoso B, Rozes N, Mas A, Guillamon JM, J. Agric. Food Chem., 53, 996 (2005)
Chaabna I, Boukhalfa C, Boutebdja O, J. Mater. Environ. Sci., 7, 1510 (2016)
Darmograi G, Prelot B, Geneste A, De Menorval LC, Zajac J, Colloids Surf. A: Physicochem. Eng. Asp., 508, 240 (2016)
Kim KR, Lee MS, Ahn DH, Yim SP, Chung H, J. Ind. Eng. Chem., 8(5), 472 (2002)
Lee SH, Kim KR, Jung CH, Chung H, Korean J. Chem. Eng., 16(5), 571 (1999)
Saad MK, Mnasri N, Mhamdi M, Chafik T, Elaloui E, Moussaoui Y, Desalin.Water Treat., 56, 2773 (2015)
Chiou MS, Li HY, J. Hazard. Mater., 93(2), 233 (2002)
Vadivelan V, Kumar KV, J. Colloid Interface Sci., 286(1), 90 (2005)
Manrique J, Martinez F, Lat. Am. J. Pharm., 26, 344 (2007)
Shaw LR, Irwin WJ, Grattan TJ, Conway BR, Drug Dev. Ind. Pharm., 31, 515 (2005)
Lindqvist N, Tuhkanen T, Kronberg L, Water Res., 39, 2219 (2005)
Mestre AS, Pires J, Nogueira JMF, Parra JB, Carvalho AP, Ania CO, Bioresour. Technol., 100(5), 1720 (2009)
Langmuir I, J. Am. Chem. Soc., 40, 1361 (1918)
Freundlich HMF, J. Phys. Chem., 57, 385 (1906)
Kumar KV, J. Hazard. Mater., 136(2), 197 (2006)
Lataye DH, Mishra IM, Mall ID, Chem. Eng. J., 138(1-3), 35 (2008)
Boulinguiez B, Le Cloirec P, Wolbert D, Langmuir, 24(13), 6420 (2008)
Foo KY, Hameed BH, Chem. Eng. J., 156(1), 2 (2010)
Sadhukhan S, Singha S, Sarkar U, Chem. Eng. J., 152(2-3), 361 (2009)
Ho YS, Carbon, 42, 2115 (2004)
Webber TW, Chakkravorti RK, AIChE J., 20, 228 (1974)
Saad MK, Khiari R, Elaloui E, Moussaoui Y, Arab. J. Chem., 7, 109 (2014)
Mestre AS, Pires J, Nogueira JMF, Carvalho AP, Carbon, 45, 1979 (2007)
Mansouri H, Carmona RJ, Gomis-Berenguer A, Souissi-Najar S, Ouederni A, Ania CO, J. Colloid Interface Sci., 449, 252 (2015)
Luo Z, Gao M, Yang S, Yang Q, Colloids Surf. A: Physicochem. Eng. Asp., 482, 222 (2015)
Yu Y, Zhuang YY, Wang ZH, Wang ZH, Qiu MQ, Chemosphere, 54, 425 (2004)
