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Received September 1, 2016
Accepted February 2, 2017
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This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
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The effects of the thermal treatment of activated carbon on the phenols adsorption
Krzysztof Kuśmierek†
Andrzej Świątkowski
Katarzyna Skrzypczyńska
Stanisław Błażewicz1
and Jakub Hryniewicz
Institute of Chemistry, Military University of Technology, Kaliskiego 2, 00-908 Warsaw, Poland 1Faculty of Materials Science and Ceramics, AGH University of Science and Technology, 30-059 Krakow, Poland
Korean Journal of Chemical Engineering, April 2017, 34(4),
10.1007/s11814-017-0015-3
10.1007/s11814-017-0015-3
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Abstract
The adsorptive properties of thermally treated activated carbon at 1,500 and 1,800 °C were investigated. The adsorption kinetics and adsorption efficiency of phenol, 4-chlorophenol and 2,4-dichlorophenol from aqueous solutions were examined. The adsorption kinetic data were analyzed using the pseudo-first and pseudo-second order models, while the equilibrium adsorption data were described by the Langmuir and Freundlich isotherms. The adsorption rate and efficiency increased in the order: phenol<4-chlorophenol<2,4-dichlorophenol. The activated carbons were also used for the modification of the carbon paste electrodes for the detection of the phenols based on the differential pulse voltammetry. Compared to the non-modified electrode, all the new paste electrodes showed a significantly greater sensitivity for the detection of the phenols. The signal response was closely related to the porosity of the materials used, and increased with an increase in the adsorption ability and the specific surface area of the modifiers.
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Rincon-Silva NG, Moreno-Pirajan JC, Giraldo L, Adsorption, 22, 33 (2016)
Strachowski P, Bystrzejewski M, Colloids Surf. A: Physicochem. Eng. Asp., 467, 113 (2015)
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Derylo-Marczewska A, Zienkiewicz-Strzalka M, Skrzypczynska K, Swiatkowski A, Kusmierek K, Adsorption, 22, 801 (2016)
