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Received July 12, 2015
Accepted October 14, 2015
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Application of Ni-doped ZnO rods for the degradation of an azo dye from aqueous solutions
Department of Environmental Health Engineering, School of Public Health, Iran University of Medical Sciences, Tehran, Iran 1Division of General Education, Kwangwoon University, Seoul 01899, Korea
Korean Journal of Chemical Engineering, March 2016, 33(3), 812-822(11), 10.1007/s11814-015-0218-4
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Abstract
Ni-doped ZnO rods were applied as a photocatalyst for the degradation of an azo dye (Reactive Black 5). Effects of solution pH, catalyst dosage, initial RB5 concentration, H2O2 concentration, different purging gases, and type of organic compounds on the removal efficiency of RB5 were studied. Ni-doped ZnO rods were synthesized by co-precipitation method. Neutral pH was selected as an optimal pH condition due to a photo-corrosion of ZnO in acidic and basic conditions. Photocatalytic degradation efficiency of RB5 was increased as the catalyst dosage increased up to 1 g/L, while it was decreased by increasing initial RB5 concentration. Pseudo-first-order rate constant (kobs) decreased from 0.122 to 0.0051 min.1 and electrical energy per order (EEo) increased from 39.34 to 941.18 (kWh/m3) by increasing RB5 concentration from 5 to 100mg/L, respectively. Photocatalytic degradation efficiency of RB5 increased by increasing H2O2 concentration, but this trend was not observed above 10 mM. Photocatalytic degradation efficiency of RB5 increased in the presence of folic acid and citric acid while interference was observed in the presence of humic acid, EDTA, oxalic acid, and phenol. Photocatalytic activity was maintained even after five successive cycles.
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Ciobanu G, Harja M, Rusu L, Mocanu AM, Luca C, Korean J. Chem. Eng., 31(6), 1021 (2014)
Mahmoudi K, Hosni K, Hamdi N, Srasra E, Korean J. Chem. Eng., 32(2), 274 (2015)
Panthi G, Park M, Kim HY, Lee SY, Park SJ, J. Ind. Eng. Chem., 21, 26 (2015)
Lucas MS, Peres JA, Dyes Pigment., 71, 236 (2006)
Shirzad-Siboni M, Khataee A, Vafaei F, Joo SW, Korean J. Chem. Eng., 31(8), 1451 (2014)
Muruganandham M, Sobana N, Swaminathan M, J. Hazard. Mater., 137(3), 1371 (2006)
Sengil IA, Ozacar M, J. Hazard. Mater., 161(2-3), 1369 (2009)
Shirzad-Siboni M, Khataee A, Joo SW, J. Ind. Eng. Chem., 20(2), 610 (2014)
Koyuncu I, Desalination, 143(3), 243 (2002)
Liu Y, Sun DZ, J. Hazard. Mater., 143(1-2), 448 (2007)
Ong SA, Ho LN, Wong YS, Raman K, Water Air Soil Pollut., 223, 1615 (2012)
Na Y, Song S, Park Y, Korean J. Chem. Eng., 22(2), 196 (2005)
Dorovskikh SI, Trubin SV, Filatov ES, Kriventsov VV, Kozlova SG, Shubin VV, Morozova NB, Igumenov IK, J. Phys. Chem. Solids, 74, 1204 (2013)
Thongrom B, Amornpitoksuk P, Suwanboon S, Baltrusaitis J, Korean J. Chem. Eng., 31(4), 587 (2014)
Ilinoiu EC, Pode R, Manea F, Colar LA, Jakab A, Orha C, Ratiu C, Lazau C, Sfarloaga P, J. Taiwan. Inst. Chem. Eng., 44, 270 (2013)
Chaudhari SP, Bodade AB, Chaudhari GN, Korean J. Chem. Eng., 30(11), 2001 (2013)
Kim Y, Lee J, Jeong H, Lee Y, Um MH, Jeong KM, Yeo MK, Kang M, J. Ind. Eng. Chem., 14(3), 396 (2008)
Soltani RDC, Rezaee A, Khataee A, Ind. Eng. Chem. Res., 52(39), 14133 (2013)
Soltani RDC, Rezaee A, Khataee AR, Safari M, J. Ind. Eng. Chem., 20(4), 1861 (2014)
Kumpika T, Thongsuwan W, Singjai P, Thin Solid Films, 516(16), 5640 (2008)
Zhao J, Wang L, Yan XQ, Yang Y, Lei Y, Zhou J, Huang YH, Gu YS, Zhang Y, Mater. Res. Bull., 46(8), 1207 (2011)
Kant S, Kumar A, Adv. Mater. Lett., 3, 350 (2012)
Raja K, Ramesh P, Geetha D, Spectroc. Acta Pt. A-Molec. Biomolec. Spectr., 120, 19 (2014)
Saharan P, Chaudhary GR, Lata S, Mehta S, Mor S, Ultrason. Sonochem., 22, 317 (2015)
Vignesh K, Rajarajan M, Suganthi A, J. Ind. Eng. Chem., 20(5), 3826 (2014)
Elilarassi R, Chandrasekaran G, Optoelectron. Lett., 6, 6 (2010)
Patterson A, Phys. Rev., 56, 978 (1939)
Kaneva NV, Dimitrov DT, Dushkin CD, Appl. Surf. Sci., 257(18), 8113 (2011)
Chang CJ, Lin CY, Hsu MH, J. Taiwan. Inst. Chem. Eng., 45, 1954 (2014)
Daneshvar N, Rasoulifard MH, Khataee AR, Hosseinzadeh F, J. Hazard. Mater., 143(1-2), 95 (2007)
Daneshvar N, Salari D, Khataee AR, J. Photochem. Photobiol. A-Chem., 162, 317 (2004)
Siboni MS, Samadi MT, Yang JK, Lee SM, Environ. Technol., 32, 1573 (2011)
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Horwitz W, Editor, Standard Methods for the Examination of Water and Wastewater, 20th Ed., APHA, Washington, DC (2000).
Shirzad-Siboni M, Khataee A, Vahid B, Joo SW, Fallah S, Curr. Nanosci., 10, 684 (2014)
Bokare A, Pai M, Athawale AA, Sol. Energy, 91, 111 (2013)
Reddy MR, Supriya V, Sugiyama M, Reddy K, Eds. Physical Investigations on ZnO: Ni Layers Deposited by Spray Pyrolysis. Conference Papers in Science; 2013: Hindawi Publishing Corporation.
Iqbal J, Wang B, Liu X, Yu D, He B, Yu R, New. J. Phys., 11, 063009 (2009)
Husain S, Rahman F, Ali N, Alvi P, J. Optoelectron. Eng., 1, 28 (2013)
Daneshvar N, Aber S, Dorraji MSS, Khataee AR, Rasoulifard MH, Sep. Purif. Technol., 58(1), 91 (2007)
Miao J, Jia Z, Lu HB, Habibi D, Zhang LC, J. Taiwan. Inst. Chem. Eng., 45, 1636 (2014)
Cai X, Cai Y, Liu Y, Li H, Zhang F, Wang Y, J. Phys. Chem. Solids, 74, 1196 (2013)
Jonidi-Jafari A, Shirzad-Siboni M, Yang JK, Naimi-Joubani M, Farrokhi M, J. Taiwan. Inst. Chem. Eng., 50, 100 (2015)
Mohagheghian A, Karimi SA, Yang JK, Shirzad-Siboni M, J. Adv. Oxid. Technol., 18, 61 (2015)
Chakrabarti S, Dutta BK, J. Hazard. Mater., 112(3), 269 (2004)
Pare B, Singh P, Jonnalgadda S, Indian J. Chem. Sect A-Inorg. Bio-Inorg. Phys. Theor. Anal. Chem., 48, 1364 (2009)
Yang JK, Lee SM, Shirzad-Siboni M, Environ. Technol., 33, 2027 (2012)
Senapati S, Srivastava SK, Singh SB, Nanoscale, 4, 6604 (2012)
Qamar M, Muneer M, Desalination, 249(2), 535 (2009)
Subramanian V, Wolf EE, Kamat PV, J. Am. Chem. Soc., 126(15), 4943 (2004)
Georgekutty R, Seery MK, Pillai SC, J. Phys. Chem. C, 112, 13563 (2008)
