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Received July 3, 2016
Accepted July 27, 2016
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Recent advances in the catalytic hydrodeoxygenation of bio-oil
Heejin Lee1
Young-Min Kim1 2
In-Gu Lee3
Jong-Ki Jeon4
Sang-Chul Jung5
Jin Do Chung6
Won Geun Choi7
Young-Kwon Park1 8†
1School of Environmental Engineering, University of Seoul, Seoul 02504, Korea 2Frontier Laboratories Ltd., 1-8-14, Saikon, Koriyama, Fukushima 963-8862, Japan 3Biomass and Waste Energy Laboratory, Korea Institute of Energy Research, Daejeon 34129, Korea 4Department of Chemical Engineering, Kongju National University, Cheonan 31080, Korea 5Department of Environmental Engineering, Sunchon National University, Suncheon 57922, Korea 6Department of Environmental Engineering, Hoseo University, Asan 336-795, Korea 7Department of Climate Change Fusion Technology, Graduate School, Hoseo University, Asan 336-795, Korea 8, Korea
catalica@uos.ac.kr
Korean Journal of Chemical Engineering, December 2016, 33(12), 3299-3315(17), 10.1007/s11814-016-0214-3
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Abstract
Owing to the increasing interest in alternative energy, there is a focus on bio-oil production from biomass because it is an abundant and renewable energy source. Among the various kinds of biomass conversion technologies, pyrolysis has been investigated widely to produce bio-oil. However, the direct use of bio-oil is difficult because of its poor quality due to the large amounts of oxygen-containing compounds, such as acids, ketones, and esters. Therefore, an additional suitable upgrading process for bio-oil is required. Hydrodeoxygenation (HDO) is considered effective for the deoxygenation of bio-oil. This paper reviews the recent progress in the catalytic HDO of bio-oil. In addition, the effects of the solvent and catalyst applied to the HDO of bio-oil are reviewed intensively together with a discussion of the deactivation behavior of the catalyst during HDO.
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