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- In relation to this article, we declare that there is no conflict of interest.
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Received April 20, 2014
Accepted November 13, 2014
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This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
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Copyright © KIChE. All rights reserved.
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Combination of maghemite and titanium oxide nanoparticles in polyvinyl alcohol-alginate encapsulated beads for cadmium ions removal
Department of Bioprocess Engineering, Faculty of Chemical Engineering, C/O Institute of Bioproduct Development (IBD), Universiti Teknologi Malaysia, 81310 UTM Johor Bahru, Johor, Malaysia
Korean Journal of Chemical Engineering, June 2015, 32(6),
10.1007/s11814-014-0333-7
10.1007/s11814-014-0333-7
Abstract
Both maghemite (γ-Fe2O3) and titanium oxide (TiO2) nanoparticles were mixed at various ratios and embedded in polyvinyl alcohol (PVA)-alginate beads. These beads were tested for photocatalytic behavior in eliminating toxic Cd(II) from the aqueous solution. The photocatalytic experiments were performed under sunlight irradiation at various pH, initial feed concentrations and γ-Fe2O3: TiO2 ratios. The recycling attribute of these beads was also investigated. The results revealed that 100% of the Cd(II) was eliminated in 150 minutes at pH 7 under sunlight. It shows that maghemite and titania PVA-alginate beads can be readily isolated from the aqueous solution after the photocatalyst process and reused for at least six times without losing their initial properties.
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Xu P, Zeng GM, Feng CL, Hu S, Zhao MH, Lai C, Wei Z, Huang C, Xie GX, Liu ZF, Sci. Total Environ., 424, 1 (2012)
Kiwi J, Gratzel M, J. Chem. Soc., 83, 1101 (2005)
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Akhavan O, Azimirad R, Appl. Catal. A: Gen., 369(1-2), 77 (2009)
Kuang SY, Yang LX, Luo SL, Cai QY, Appl. Surf. Sci., 255(16), 7385 (2009)
Liu H, Shon HK, Sun XA, Vigneswaran S, Nan H, Appl. Surf. Sci., 257(13), 5813 (2011)
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Jeong Y, Fan M, Singh S, Chuang CL, Saha B, van Leeuwen H, Chem. Eng. Process., 46(10), 1030 (2007)
Chen CL, Hu J, Shao DD, Li JX, Wang XK, J. Hazard. Mater., 164(2-3), 923 (2009)
Lee I, Park JA, Kang JK, Kim JH, Son JW, Yi IG, Kim SB, Environ. Eng. Res., 19, 157 (2014)
Idris A, Misran E, Yusof NM, J. Ind. Eng. Chem., 18(6), 2151 (2012)
Rahman M, Misran E, Idris A, Yusof NM, J. Technol., 67, 5 (2014)
Idris A, Ismail NSM, Hassan N, Misran E, Ngomsik AF, J. Ind. Eng. Chem., 18(5), 1582 (2012)
Idris A, Majidnia Z, Desalin. Water Treat., 10.1080/19443994.2014.940396, 1 (2014)
Thapa R, Maiti S, Rana TH, Maiti UN, Chattopadhyay KK, J. Mol. Catal. A-Chem., 363, 223 (2012)
Idris A, Hassan N, Mohd Ismail NS, Misran E, Yusof NM, Ngomsik AF, Bee A, Water Res., 44, 1683 (2010)
Idris A, Hassan N, Rashid R, Ngomsik AF, J. Hazard. Mater., 186(1), 629 (2011)
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Saeed A, Akhter MW, Iqbal M, Sep. Purif. Technol., 45(1), 25 (2005)
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Apiratikul R, Marhaba TF, Wattanachira S, Pavasant P, J. Sci. Technol., 26, 199 (2004)
Chen F, Shi R, Xue Y, Chen L, Wan QH, J. Magn. Magn. Mater., 322, 2439 (2010)
Mohapatra P, Samantaray SK, Parida K, J. Photochem. Photobiol. A-Chem., 170, 189 (2005)
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Cong YQ, Li Z, Zhang Y, Wang Q, Xu Q, Chem. Eng. J., 191, 356 (2012)
Kuang SY, Yang LX, Luo SL, Cai QY, Appl. Surf. Sci., 255(16), 7385 (2009)
Ho YS, McKay G, Water Res., 33, 585 (1999)

