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Received June 30, 2013
Accepted December 28, 2013
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Factorial design in optimization of the separation of uranium from yellowcake across a hollow fiber supported liquid membrane, with mass transport modeling
Chromatography and Separation Research Unit, Department of Chemistry, Faculty of Science, Chulalongkorn University, Patumwan, Bangkok 10330, Thailand 1Department of Chemical Engineering, Faculty of Engineering, Chulalongkorn University, Patumwan, Bangkok 10330, Thailand, Korea 2Government Pharmaceutical Organization, Ratchathevi, Bangkok 10400, Thailand 3Department of Chemical Engineering, Faculty of Engineering and Industrial Technology, Silpakorn University, Nakhon Pathom 73000, Thailand
prakorn@su.ac.th, korn_mass_transfer@hotmail.com
Korean Journal of Chemical Engineering, May 2014, 31(5), 868-874(7)
https://doi.org/10.1007/s11814-013-0294-2
https://doi.org/10.1007/s11814-013-0294-2
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Abstract
The extraction and stripping of uranium(VI) from other impurity elements in yellowcake was performed simultaneously in one stage by a hollow fiber supported liquid membrane. Uranium ions were selectively extracted from yellowcake using TBP as the extractant, while thorium and some rare earth elements were rejected in the raffinate. The optimization method was carried out using 32 factorial design. The concentration of nitric acid in the feed solution and the concentration of TBP in the liquid membrane were regarded as factors in the optimization. A mass transport model focusing on the boundary layer of the extraction side was also applied. The model can predict the concentration of uranium in the feed tank at different times. The validity of the developed model was statistically evaluated through a comparison with experimental data, and good agreement was obtained.
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Hughes KC, Singh R, Hydrometallurgy, 6, 25 (1980)
Amaral JCBS, Morais CA, Miner. Eng., 23, 498 (2010)
Sato T, J. Appl. Chem., 15, 489 (1965)
Marchese J, Campderros M, Desalination, 164(2), 141 (2004)
Klaassen R, Feron PHM, Jansen AE, Chem. Eng. Res. Des., 83(A3), 234 (2005)
Gabelman A, Hwang ST, J. Membr. Sci., 159(1-2), 61 (1999)
Kedari CS, Pandit SS, Gandhi PM, J. Membr. Sci., 430, 188 (2013)
Manna MS, Bhatluri KK, Saha P, Ghoshal AK, J. Membr. Sci., 447, 325 (2013)
Schultz G, Desalination, 68, 191 (1988)
Kislik VS (Ed.), Liquid membranes: principles & applications in chemical separations & wastewater treatment, Elsevier, Oxford UK, 401 (2010)
Ho WSW, Sirkar KK, Membrane handbook, Chapman & Hall, New York (1992)
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Ramakul P, Supajaroon T, Prapasawat T, Pancharoen U, Lothongkum AW, J. Ind. Eng. Chem., 15(2), 224 (2009)
Ramakul P, Leepipatpiboon N, Yamoum C, Thubsuang U, Bunnak S, Pancharoen U, Korean J. Chem. Eng., 26(3), 765 (2009)
Sunsandee N, Pancharoen U, Rashatasakhon P, Ramakul P, Leepipatpiboon N, Sep. Sci. Technol., 48(15), 2363 (2013)
Sunsandee N, Leepipatpiboon N, Ramakul P, Korean J. Chem. Eng., 30(6), 1312 (2013)
Peace GS, Taguchi methods: a hands-on approach, Addison-Wesley, Reading MA (1993)
Guervenou J, Giamarchi P, Coulouarn C, Guerda M, Le Lez C, Oboyet T, Chemom. Intell. Lab. Syst., 63, 81 (2002)
da Silva JCGE, Dias JRM, Magalhaes JMCS, Anal. Chim. Acta, 450, 175 (2001)
Medjahed B, Didi MA, Villemin D, Desalin. Water Treat., In Press (2013)
Kavak D, Demir M, Bassayel B, Anagun AS, Desalin. Water Treat., 51, 1712 (2013)
Ura P, Prakorn R, Weerawat P, Milan H, J. Ind. Eng. Chem., 12(5), 673 (2006)
Pathak PN, Veeraraghavan R, Prabhu DR, Mahajan GR, Manchanda VK, Sep. Sci. Technol., 34(13), 2601 (1999)
Stas J, Dahdouh A, Shlewit H, Periodica Polytechnica : Chem. Eng., 49, 3 (2005)
Bird RB, Stewart WE, Lightfoot EN, Transport phenomena, 2nd Ed., John Wiley & Sons, New York (2007)
De Soete D, Gijbels R, Hoste J, Neutron activation analysis, John Wiley & Sons, New York (1972)
Ehmann WD, Vance DE, Radiochemistry and nuclear methods of analysis, John Wiley & Sons, New York (1991)
Yang Q, Kocherginsky NM, J. Membr. Sci., 297(1-2), 121 (2007)
Robinson RA, Stokes RH, Electrolyte solutions, Butterworth, London (1965)
Mauerhofer E, Zhernosekov K, Rosch F, Radiochim. Acta, 91, 473 (2003)
O’Rourke N, Hatcher L, Stepanksi EJ, A step-by-step approach to using SAS for univariate & multivariate statistics, 2nd Ed., SAS Institute, Cary NC (2005)
