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- In relation to this article, we declare that there is no conflict of interest.
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Received March 11, 2014
Accepted April 29, 2014
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This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
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Copyright © KIChE. All rights reserved.
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LaMer diagram approach to study the nucleation and growth of Cu2O nanoparticles using supersaturation theory
Materials and Metallurgical Engineering Department, Advanced Materials Research Center, Sahand University of Technology, Tabriz, Iran
Korean Journal of Chemical Engineering, November 2014, 31(11), 2020-2026(7), 10.1007/s11814-014-0130-3
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Abstract
Uptake to cuprous oxide (Cu2O) nanoparticle synthesis with various particle sizes and shapes via supersaturation chemistry approach (LaMer model) has been conducted. Ascorbic acid and maltodextrine as reducing agents and polyvinylpyrrolidone (PVP) as a surfactant were utilized for synthesis of Cu2O nanoparticles in aqueous solution. The narrow particle size range was achieved by controlling the kinetics of nucleation and growth of particles to satisfy LaMer theory. This mean was performed utilizing different reducing agents (ascorbic acid and maltodextrin) and also, changing the reducing agent addition condition. The results showed the reducing agent addition condition, varying the size of Cu2O nanoparticles from 89 nm to 74 nm for drop-wisely and at-once routes, respectively. The samples were characterized by XRD, SEM, and UV-Vis spectroscopy. The results indicate the shape of as-prepared cuprous oxide nanoparticles have close relationship with thermodynamic and kinetic conditions, and also reducing addition condition.
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