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Received May 31, 2013
Accepted September 26, 2013
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Electrochemical properties related to the thickness control of the solid oxide fuel cell component layer using decalcomania paper
1Energy Efficient Materials Team, Korea Institute of Ceramic Engineering and Technology, Seoul 153-801, Korea 2Department of Chemical Engineering, Graduate School of Engineering, Inha University, Incheon 402-751, Korea
psm@kicet.re.kr
Korean Journal of Chemical Engineering, January 2014, 31(1), 50-55(6)
https://doi.org/10.1007/s11814-013-0187-4
https://doi.org/10.1007/s11814-013-0187-4
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Abstract
We fabricated anode-supported solid oxide fuel cells using decalcomania paper. To investigate the changes in thickness of the component layer and electrical properties in a unit cell, the number of layers of cathodes and the electrolyte decalcomania paper is changed. As a result, the thickness of the electrolyte and cathode layer regularly increases with an increase in the number of decalcomania papers attached. In addition, when only one electrolyte decalcomania_x000D_
paper is attached to an anode support, a tight and dense 8 μm electrolyte layer is obtained. A unit cell with a cathode thickness of 120 μm to which decalcomania paper is attached nine times is shown to have an open circuit voltage (OCV) of 1.08 V and a maximum power density (MPD) of 902 mW cm^(-2) at 800 ℃.
Keywords
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Vanherle J, Mcevoy AJ, Thampi KR, Electrochim. Acta, 41(9), 1447 (1996)
Choi JJ, Qin WT, Liu MF, Liu ML, J. Am. Ceram. Soc., 94(10), 3340 (2011)
Wang Z, Qian J, Cao J, Wang S, Wen T, J. Alloys Compounds., 437, 264 (2007)
Hassan AAE, Menzler NH, Blass G, Ali ME, Buchkremer HP, Stover D, J. Mater. Sci., 37(16), 3467 (2002)
Ried P, Lorenz C, Bronstrup A, Graule T, Menzler NH, Sitte W, Holtappels P, J. European Ceram. Soc., 28, 1801 (2008)
Zhao L, Huang X, Zhu R, Lu Z, Sun W, Zhang Y, Ge X, Liu Z, Su W, J. Phys. Chem. Solids., 69, 2019 (2008)
Bai Y, Liu J, Wang C, J. Hydrog. Energy., 34, 7311 (2009)
Will J, Mitterdorfer A, Kleinlogel C, Perednis D, Gauckler LJ, Solid State Ion., 131(1-2), 79 (2000)
Kharton VV, Marques FMB, Atkinson A, Solid State Ion., 174(1-4), 135 (2004)
Fukui T, Ohara S, Naito M, Nogi K, J. Nano. Res., 3, 171 (2001)
Haanappel VAC, Mertens J, Rutenbeck D, Tropartz C, Herzhof W, Sebold D, Tietz F, J. Power Sources, 141(2), 216 (2005)
