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Received August 2, 2012
Accepted December 16, 2012
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This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
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Chiral adsorption of phenylalanine by α-, β-cyclodextrin modified layered double hydroxides
Chemical Engineering Department, Zibo Vocational Institute, Zibo 255314, P. R. China
lxl5233@163.com
Korean Journal of Chemical Engineering, April 2013, 30(4), 918-924(7)
https://doi.org/10.1007/s11814-012-0217-7
https://doi.org/10.1007/s11814-012-0217-7
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Abstract
The chiral adsorption of racemic phenylalanine (Phe) by carboxymethyl-α/β-cyclodextrin-intercalated Zn-Al layered double hydroxides (CM-α/β-CD-LDHs) has been studied. The adsorption isotherms of chiral excess adsorption and the total adsorption of Phe by these CM-α/β-CD-LDHs have been investigated. CM--CD-LDHs were found to be more suitable for chiral recognition of Phe than CM--CD-LDHs. Furthermore, the intraparticle diffusion model is successfully validated in this work. Intraparticle effective diffusivities (Deff) of Phe in these CM-α/β-CD-LDHs macroparticles were determined from the homogeneous Fickian diffusion model at various temperatures.
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Ravoo BJ, Darcy R, Mazzaglia A, Nolan D, Gaffney K, Chem.Commun., 827 (2001)
