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Received November 23, 2011
Accepted November 5, 2012
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H2S oxidation by multi-wall carbon nanotubes decorated with tungsten sulfide
Gas Research Division, Research Institute of Petroleum Industry, West Boulevard, Azadi Sport Complex, Tehran 14665-1998, Iran 1Department of Chemical Engineering, Tarbiat Modares University, Aleahmad Highway, Tehran 14115-143, Iran
alizadehsa@ripi.ir
Korean Journal of Chemical Engineering, April 2013, 30(4), 871-877(7)
https://doi.org/10.1007/s11814-012-0190-1
https://doi.org/10.1007/s11814-012-0190-1
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Abstract
Tungsten sulfide catalysts decorated on single and multiwall carbon nanotubes (SWNTs & MWNTs) and activated carbon were synthesized, and XRD, ICP, SEM, TEM and ASAP analyses were employed to acquire the characteristics of each catalyst. Afterwards a gas flow containing 5,000 ppm of H2S was passed over the catalyst in gas hour space velocity (GHSV) of 5,000 h^(-1), temperature of 65 ℃, steam volume percent of 20 and O2/H2S ratio equal to 2. The results revealed that the catalyst supported on MWNTs exhibited higher conversion amongst its counterparts. Then effects of GHSV, steam volume percent in the feed, catalyst loading and temperature were investigated on conversion of hydrogen sulfide to elemental sulfur for tungsten sulfide catalyst decorated on MWNTs.
Keywords
References
Gas Processors Suppliers Association, Engineering Data Book, Vol. 2, 12th Ed. (2004)
Maddox RN, Gas and Liquid Sweetening, Campbell Petroleum Series, Oklahoma (1998)
Pahlavanzadeh H, Farazar M, Korean J. Chem. Eng., 26(4), 1112 (2009)
Wang R, Sep. Purif. Technol., 31(1), 111 (2003)
Mikhail S, Zaki T, Khalil L, Appl. Catal. A: Gen., 227(1-2), 265 (2002)
Funks HH, Fraenkel D, Houlding VH, US Patent, 96,049 A1 (2002)
Graham J, Yaun C, US Patent, 6,858,192 B2 (2005)
Laperdrix E, Sahibed-dine A, Costentin G, Bensitel M, Lavalley JC, Appl. Catal. B: Environ., 27(2), 137 (2000)
Monnery WD, Hawboldt KA, Pollock A, Svrcek WY, Chem. Eng. Sci., 55(21), 5141 (2000)
Chung JS, Paik SC, Kim HS, Lee DS, Nam IS, Catal. Today, 35(1-2), 37 (1997)
Mendioroz S, Munoz V, Alvarez E, Palacios JM, Appl. Catal. A: Gen., 132(1), 111 (1995)
Rolke D, Cornel P, Lell R, Stetzer K, Neuroth G, US Patent, 5,256,384 (1993)
Graham JR, Cheng J, US Patent, 7,241,430 B2 (2007)
Wang L, Cao B, Wang SD, Yuan Q, Chem. Eng. J., 118(3), 133 (2006)
Miller R, US Patent, 3,672,125 (1972)
Chun SW, Jang JY, Park DW, Woo HC, Chung JS, Appl. Catal. B: Environ., 16(3), 235 (1998)
Jung SJ, Kim MH, Chung JK, Moon MJ, Chung JS, Park DW, Woo HC, Stud. Surf. Sci. Catal., 146, 621 (2003)
Bineesh KV, Kim DK, Cho HJ, Park DW, J. Ind. Eng. Chem., 16(4), 593 (2010)
Keller E, Ramani S, Allison D, Lusk S, Hatcher N, Swinney L, Kirkendall K, Torres G, Stewart P, Pruitt T, US Patent, 7,226,572 B1 (2007)
Carlsson A, Heeringen VGJ, US Patent, 0,047,201 A1 (2009)
Nguyen P, Edouard D, Nhut JM, Ledoux MJ, Pham C, Pham-Huu C, Appl. Catal. B: Environ., 76(3-4), 300 (2007)
Keller N, Pham-Huu C, Ledoux MJ, Appl. Catal. A: Gen., 217(1-2), 205 (2001)
Nguyen D, Bandosz T, Micropor. Mesopor. Mater., 92, 47 (2006)
Klein J, Henning D, Fuel., 63, 1064 (1984)
Yasyerli S, Dogu G, Dogu T, Catal. Today, 117(1-3), 271 (2006)
Bashkova S, Baker FS, Wu X, Armstrong TR, Schwartz V, Carbon., 45, 1354 (2007)
Bagreev A, Bandoz TJ, Carbon., 39, 2303 (2001)
Primavera A, Trovarelli A, Andreussi P, Dolcetti G, Appl. Catal. A: Gen., 173(2), 185 (1998)
Adib A, Bagreev A, Bandosz TJ, Environ. Sci. Technol., 34, 686 (2000)
Bandosz TJ, Carbon., 37, 483 (1999)
Bandosz TJ, J. Colloid Interface Sci., 246(1), 1 (2002)
Shang H, Liu C, Xu Y, Qiu J, Wei F, J. Nat. Gas Chem., 15, 203 (2006)
Nhut JM, Huu CP, Keller N, Ledoux MJ, Catal. Today., 92, 91 (2004)
Rashidi AM, Akbarnejad MM, Khodadadi AA, Mortazavi Y, Ahmadpour A, Nanotechnol., 18, 315605 (2007)
Mohamadalizadeh A, Towfighi J, Rashidi A, Mohajeri A, Golkar M, Ind. Eng. Chem. Res., 50(13), 8050 (2011)
Mohamadalizadeh A, Towfighi J, Rashidi A, Manteghian M, Mohajeri A, Arasteh R, Korean J. Chem. Eng., 28(5), 1221 (2011)
Habibi R, Rashidi AM, Daryan JT, Zadeh AMA, Appl. Surf. Sci., 257(2), 434 (2010)
Guana L, Lia H, Shi Z, Gu Z, Solid State Commun., 141, 459 (2007)
Mohamadalizadeh A, Towfighi J, Rashidi AM, Mohajeri A, Sattari S, Manteghian M, US Patent, 168,018 A1 (2011)
Maddox RN, Gas and Liquid Sweetening, Campbell Petroleum Series, Oklahoma (1998)
Pahlavanzadeh H, Farazar M, Korean J. Chem. Eng., 26(4), 1112 (2009)
Wang R, Sep. Purif. Technol., 31(1), 111 (2003)
Mikhail S, Zaki T, Khalil L, Appl. Catal. A: Gen., 227(1-2), 265 (2002)
Funks HH, Fraenkel D, Houlding VH, US Patent, 96,049 A1 (2002)
Graham J, Yaun C, US Patent, 6,858,192 B2 (2005)
Laperdrix E, Sahibed-dine A, Costentin G, Bensitel M, Lavalley JC, Appl. Catal. B: Environ., 27(2), 137 (2000)
Monnery WD, Hawboldt KA, Pollock A, Svrcek WY, Chem. Eng. Sci., 55(21), 5141 (2000)
Chung JS, Paik SC, Kim HS, Lee DS, Nam IS, Catal. Today, 35(1-2), 37 (1997)
Mendioroz S, Munoz V, Alvarez E, Palacios JM, Appl. Catal. A: Gen., 132(1), 111 (1995)
Rolke D, Cornel P, Lell R, Stetzer K, Neuroth G, US Patent, 5,256,384 (1993)
Graham JR, Cheng J, US Patent, 7,241,430 B2 (2007)
Wang L, Cao B, Wang SD, Yuan Q, Chem. Eng. J., 118(3), 133 (2006)
Miller R, US Patent, 3,672,125 (1972)
Chun SW, Jang JY, Park DW, Woo HC, Chung JS, Appl. Catal. B: Environ., 16(3), 235 (1998)
Jung SJ, Kim MH, Chung JK, Moon MJ, Chung JS, Park DW, Woo HC, Stud. Surf. Sci. Catal., 146, 621 (2003)
Bineesh KV, Kim DK, Cho HJ, Park DW, J. Ind. Eng. Chem., 16(4), 593 (2010)
Keller E, Ramani S, Allison D, Lusk S, Hatcher N, Swinney L, Kirkendall K, Torres G, Stewart P, Pruitt T, US Patent, 7,226,572 B1 (2007)
Carlsson A, Heeringen VGJ, US Patent, 0,047,201 A1 (2009)
Nguyen P, Edouard D, Nhut JM, Ledoux MJ, Pham C, Pham-Huu C, Appl. Catal. B: Environ., 76(3-4), 300 (2007)
Keller N, Pham-Huu C, Ledoux MJ, Appl. Catal. A: Gen., 217(1-2), 205 (2001)
Nguyen D, Bandosz T, Micropor. Mesopor. Mater., 92, 47 (2006)
Klein J, Henning D, Fuel., 63, 1064 (1984)
Yasyerli S, Dogu G, Dogu T, Catal. Today, 117(1-3), 271 (2006)
Bashkova S, Baker FS, Wu X, Armstrong TR, Schwartz V, Carbon., 45, 1354 (2007)
Bagreev A, Bandoz TJ, Carbon., 39, 2303 (2001)
Primavera A, Trovarelli A, Andreussi P, Dolcetti G, Appl. Catal. A: Gen., 173(2), 185 (1998)
Adib A, Bagreev A, Bandosz TJ, Environ. Sci. Technol., 34, 686 (2000)
Bandosz TJ, Carbon., 37, 483 (1999)
Bandosz TJ, J. Colloid Interface Sci., 246(1), 1 (2002)
Shang H, Liu C, Xu Y, Qiu J, Wei F, J. Nat. Gas Chem., 15, 203 (2006)
Nhut JM, Huu CP, Keller N, Ledoux MJ, Catal. Today., 92, 91 (2004)
Rashidi AM, Akbarnejad MM, Khodadadi AA, Mortazavi Y, Ahmadpour A, Nanotechnol., 18, 315605 (2007)
Mohamadalizadeh A, Towfighi J, Rashidi A, Mohajeri A, Golkar M, Ind. Eng. Chem. Res., 50(13), 8050 (2011)
Mohamadalizadeh A, Towfighi J, Rashidi A, Manteghian M, Mohajeri A, Arasteh R, Korean J. Chem. Eng., 28(5), 1221 (2011)
Habibi R, Rashidi AM, Daryan JT, Zadeh AMA, Appl. Surf. Sci., 257(2), 434 (2010)
Guana L, Lia H, Shi Z, Gu Z, Solid State Commun., 141, 459 (2007)
Mohamadalizadeh A, Towfighi J, Rashidi AM, Mohajeri A, Sattari S, Manteghian M, US Patent, 168,018 A1 (2011)
