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Received August 14, 2012
Accepted January 15, 2013
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This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
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Copyright © KIChE. All rights reserved.
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TiO2 nanotube-supported V2O5 catalysts for selective NO reduction by NH3
School of Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, P. R. China
zq304@mail.njust.edu.cn
Korean Journal of Chemical Engineering, April 2013, 30(4), 836-841(6)
https://doi.org/10.1007/s11814-013-0008-9
https://doi.org/10.1007/s11814-013-0008-9
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Abstract
TiO2 nanotubes (TNT) were prepared by hydrothermal method at 140 ℃ for 23 h. The V2O5/TNT (VTNT) catalysts were obtained by impregnation in NH4VO3 solution. The VTNTs exhibited much higher denitration efficiency than those supported on the raw TiO2, and satisfactory resistance to water and sulfur. Results from BET, TEM, XRD, NH3-TPD and EPR verified that V2O5 was dispersed well on TNT, thus favoring NH3 adsorption, promoting the transformation from V5+ to V4+, conducing to the formation of oxygen vacancies and superoxide radicals in the presence_x000D_
of NH3 and O2, and then resulting in the high catalytic activity of VTNTs.
Keywords
References
Lopez GJ, Polupan G, Velazquez MT, Leyte RL, Appl.Therm. Eng., 29, 1614 (2009)
Zhang XL, Huang ZG, Liu ZY, Catal. Commun., 9, 842 (2008)
Long RQ, Yang RT, Appl. Catal. B: Environ., 27(2), 87 (2000)
Bosch H, Janssen F, Catal. Today., 2, 369 (1988)
Wood SC, Chem. Eng. Prog., 90(1), 32 (1994)
Tol MFHV, Quinlan MA, Luck F, Somorjai GA, Nieuwenhuys BE, J. Catal., 129, 186 (1991)
Heck RM, Catal. Today, 53(4), 519 (1999)
Long RQ, Yang RT, Chang R, Chem. Commun., 57, 452 (2002)
Chen JP, Buzanowski MA, Yang RT, Cichanowicz JE, J. Air Waste Manage., 40, 1403 (1990)
Pena DA, Uphade BS, Smirniotis PG, J. Catal., 221(2), 421 (2004)
Huang Y, Tong Z, Wu B, Zhang JF, J. Fuel. Chem. Technol., 36, 616 (2008)
Li Q, Yang HS, Nie AM, Fan XY, Zhang XB, Catal. Lett., 141(8), 1237 (2011)
Giakoumelou I, Fountzoula C, Kordulis C, Boghosian S, Catal. Today, 73(3-4), 255 (2002)
Higashimoto S, Tanihata W, Nakagawa Y, Azuma M, Ohue H, Sakata Y, Appl. Catal. A: Gen., 98, 104 (2008)
Li YT, Zhong Q, J. Hazard. Mater., 172(2-3), 635 (2009)
Reddy BM, Chowdhury B, Ganesh I, Reddy EP, Rojas TC, Fernandez A, J. Phys. Chem. B, 102(50), 10176 (1998)
Reddy BM, Ganesh I, Reddy EP, J. Phys. Chem. B, 101(10), 1769 (1997)
Huang BC, Huang R, Jin DJ, Ye DQ, Catal. Today, 126(3-4), 279 (2007)
Marban G, Antuna R, Fuertes AB, Appl. Catal. B: Environ., 41(3), 323 (2003)
Zanella R, Giorgio S, Henry CR, Louis C, J. Phys. Chem. B, 106(31), 7634 (2002)
Chen SA, Nian JN, Tsai CC, Teng H, J. Air Waste Manage. Assoc., 57, 600 (2007)
Hinz A, Larsson PO, Skarman B, Andersson A, Appl. Catal. B: Environ., 34(2), 161 (2001)
Chmielarz L, Kustrowski P, Dziembaj R, Cool P, Vansant EF, Appl. Catal. B: Environ., 62(3-4), 369 (2006)
Hsieh CT, Fan WS, Chen WY, Lin JY, Sep. Purif. Technol., 67(3), 312 (2009)
Kasuga T, Hiramatsu M, Hoson A, Sekino T, Niihara K, Langmuir, 14(12), 3160 (1998)
Du GH, Chen Q, Che RC, Yuan ZY, Peng LM, Appl. Phys.Lett., 79, 3702 (2001)
Chen Q, Zhou WZ, Du GH, Peng LM, Adv. Mater., 14(17), 1208 (2002)
Kong XY, Ding Y, Yang R, Wang ZL, Science., 303, 1348 (2004)
Wang DA, Zhou F, Liu Y, Liu WM, Mater. Lett., 62, 1819 (2008)
Zhao ZH, Fan JM, Wang JY, Li RF, Catal. Commun., 21, 32 (2012)
Shen BX, Yao Y, Ma HQ, Liu T, Chin. J. Catal., 32, 1803 (2011)
Yin XL, Han HM, Gunji I, Endou A, Ammal SSC, Kubo M, Miyamoto A, J. Phys. Chem. B, 103(22), 4701 (1999)
Ramis G, Yi L, Busca G, Turco M, Kotur E, Willey RJ, J. Catal., 157(2), 523 (1995)
Liu QY, Liu ZY, Li CY, Chin. J. Catal., 27, 636 (2006)
Xu HT, Shen YS, Shao CH, Lin FW, Zhu SM, Xiu T, J. Rare Earth., 28, 721 (2010)
Dong LH, Sun CZ, Tang CJ, Zhang B, Zhu J, Liu B, Gao F, Hu YH, Dong L, Chen Y, Appl. Catal. A: Gen., 431, 126 (2012)
Zhang SL, Li HY, Zhong Q, Appl. Catal. A: Gen., 435, 156 (2012)
Long RQ, Yang RT, J. Catal., 207(2), 158 (2002)
Zhu ZP, Liu ZY, Liu SJ, Niu HX, Appl. Catal. B: Environ., 23(4), 229 (1999)
Muniz J, Marban G, Fuertes AB, Appl. Catal. B: Environ., 27(1), 27 (2000)
Nova I, Lietti L, Tronconi E, Forzatti P, Catal. Today, 60(1-2), 73 (2000)
Zhang XL, Huang ZG, Liu ZY, Catal. Commun., 9, 842 (2008)
Long RQ, Yang RT, Appl. Catal. B: Environ., 27(2), 87 (2000)
Bosch H, Janssen F, Catal. Today., 2, 369 (1988)
Wood SC, Chem. Eng. Prog., 90(1), 32 (1994)
Tol MFHV, Quinlan MA, Luck F, Somorjai GA, Nieuwenhuys BE, J. Catal., 129, 186 (1991)
Heck RM, Catal. Today, 53(4), 519 (1999)
Long RQ, Yang RT, Chang R, Chem. Commun., 57, 452 (2002)
Chen JP, Buzanowski MA, Yang RT, Cichanowicz JE, J. Air Waste Manage., 40, 1403 (1990)
Pena DA, Uphade BS, Smirniotis PG, J. Catal., 221(2), 421 (2004)
Huang Y, Tong Z, Wu B, Zhang JF, J. Fuel. Chem. Technol., 36, 616 (2008)
Li Q, Yang HS, Nie AM, Fan XY, Zhang XB, Catal. Lett., 141(8), 1237 (2011)
Giakoumelou I, Fountzoula C, Kordulis C, Boghosian S, Catal. Today, 73(3-4), 255 (2002)
Higashimoto S, Tanihata W, Nakagawa Y, Azuma M, Ohue H, Sakata Y, Appl. Catal. A: Gen., 98, 104 (2008)
Li YT, Zhong Q, J. Hazard. Mater., 172(2-3), 635 (2009)
Reddy BM, Chowdhury B, Ganesh I, Reddy EP, Rojas TC, Fernandez A, J. Phys. Chem. B, 102(50), 10176 (1998)
Reddy BM, Ganesh I, Reddy EP, J. Phys. Chem. B, 101(10), 1769 (1997)
Huang BC, Huang R, Jin DJ, Ye DQ, Catal. Today, 126(3-4), 279 (2007)
Marban G, Antuna R, Fuertes AB, Appl. Catal. B: Environ., 41(3), 323 (2003)
Zanella R, Giorgio S, Henry CR, Louis C, J. Phys. Chem. B, 106(31), 7634 (2002)
Chen SA, Nian JN, Tsai CC, Teng H, J. Air Waste Manage. Assoc., 57, 600 (2007)
Hinz A, Larsson PO, Skarman B, Andersson A, Appl. Catal. B: Environ., 34(2), 161 (2001)
Chmielarz L, Kustrowski P, Dziembaj R, Cool P, Vansant EF, Appl. Catal. B: Environ., 62(3-4), 369 (2006)
Hsieh CT, Fan WS, Chen WY, Lin JY, Sep. Purif. Technol., 67(3), 312 (2009)
Kasuga T, Hiramatsu M, Hoson A, Sekino T, Niihara K, Langmuir, 14(12), 3160 (1998)
Du GH, Chen Q, Che RC, Yuan ZY, Peng LM, Appl. Phys.Lett., 79, 3702 (2001)
Chen Q, Zhou WZ, Du GH, Peng LM, Adv. Mater., 14(17), 1208 (2002)
Kong XY, Ding Y, Yang R, Wang ZL, Science., 303, 1348 (2004)
Wang DA, Zhou F, Liu Y, Liu WM, Mater. Lett., 62, 1819 (2008)
Zhao ZH, Fan JM, Wang JY, Li RF, Catal. Commun., 21, 32 (2012)
Shen BX, Yao Y, Ma HQ, Liu T, Chin. J. Catal., 32, 1803 (2011)
Yin XL, Han HM, Gunji I, Endou A, Ammal SSC, Kubo M, Miyamoto A, J. Phys. Chem. B, 103(22), 4701 (1999)
Ramis G, Yi L, Busca G, Turco M, Kotur E, Willey RJ, J. Catal., 157(2), 523 (1995)
Liu QY, Liu ZY, Li CY, Chin. J. Catal., 27, 636 (2006)
Xu HT, Shen YS, Shao CH, Lin FW, Zhu SM, Xiu T, J. Rare Earth., 28, 721 (2010)
Dong LH, Sun CZ, Tang CJ, Zhang B, Zhu J, Liu B, Gao F, Hu YH, Dong L, Chen Y, Appl. Catal. A: Gen., 431, 126 (2012)
Zhang SL, Li HY, Zhong Q, Appl. Catal. A: Gen., 435, 156 (2012)
Long RQ, Yang RT, J. Catal., 207(2), 158 (2002)
Zhu ZP, Liu ZY, Liu SJ, Niu HX, Appl. Catal. B: Environ., 23(4), 229 (1999)
Muniz J, Marban G, Fuertes AB, Appl. Catal. B: Environ., 27(1), 27 (2000)
Nova I, Lietti L, Tronconi E, Forzatti P, Catal. Today, 60(1-2), 73 (2000)
