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Received September 9, 2011
Accepted November 14, 2011
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This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
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Influence of sodium dodecyl sulfate and cetyl trimethylammonium bromide upon calcium carbonate precipitation on bacterial cellulose
Marta Stroescu
Anicuta Stoica-Guzun†
Sorin Ion Jinga
Tanase Dobre
Iuliana Mihaela Jipa
Loredana Mihaela Dobre
Faculty of Applied Chemistry and Materials Science, Politehnica University of Bucharest, Polizu 1-3, Bucharest 011061, Romania
stoica.anicuta@gmail.com
Korean Journal of Chemical Engineering, September 2012, 29(9), 1216-1223(8)
https://doi.org/10.1007/s11814-011-0290-3
https://doi.org/10.1007/s11814-011-0290-3
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Abstract
Calcium carbonate was deposed on bacterial cellulose (BC) never-dried membranes in the presence of different concentrations of sodium dodecyl sulfate (SDS) and cetyl trimethylammonium bromide (CTAB) by a precipitation reaction between aqueous solutions of calcium chloride (CaCl2) and sodium carbonate (Na2CO3) containing, or not, surfactant in their composition. Different shapes of crystals were obtained from rhombohedral ones to flowerlike,_x000D_
depending on surfactant type and concentration. From the two surfactants tested, SDS has a greater influence on calcium carbonate morphology than CTAB. The only polymorph obtained in all studied cases was calcite. The composite films BC-calcite were characterized by means of scanning electron microscopy (SEM), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR) and color measurements. The obtained BC-calcium carbonate composites_x000D_
could be used in paper manufacturing.
Keywords
References
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Malkaj P, Dalas E, Kanellopoulou DG, Chrissanthopoulos A, Sevastos D, Powder Technol., 177(2), 71 (2007)
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Padalkar KV, Gaikar VG, Aswal VK, J. Molecular Liquids., 144, 40 (2009)
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