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Received December 11, 2010
Accepted June 10, 2011
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Adsorptive separation of carbon dioxide by polyethyleneimine modified adsorbents
Greenhouse Gas Research Center, Korea Institute of Energy Research, 71-2, Jang-dong, Yuseong-gu, Daejeon 305-343, Korea 1Carbon Dioxide Reduction & Sequestration R&D Center, Korea Institute of Energy Research, 71-2, Jang-dong, Yuseong-gu, Daejeon 305-343, Korea
ihbaek@kier.re.kr
Korean Journal of Chemical Engineering, February 2012, 29(2), 249-262(14), 10.1007/s11814-011-0158-6
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Abstract
Utilization of carbon dioxide (CO2) has become an important global issue due to significant and continuous rise in atmospheric CO2 concentrations. To find a potential solution, two types of mesoporous materials, MCM-41 and MCM-48, were synthesized and impregnated with 30, 50 and 70 wt% of polyethyleneimine (PEI) in methanol to evaluate the performance of the materials in terms of CO2 adsorption. The materials were characterized by XRD, TGA, FTIR,TEM, SEM, N2-physisorption and BET techniques. All the PEI-loaded materials exhibited substantially higher reversible CO2 adsorption-desorption behaviors with >99% recovery. The above study proved that MCM-48 is a better material as compared to MCM-41 for loading of PEI. The material with 50 wt% loading of PEI on MCM-48, showed maximum adsorption of 248 mg/g-PEI at 80℃ which is about 30 times higher than that of MCM-48 and about 2.3 times that of pure PEI.
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References
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