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In relation to this article, we declare that there is no conflict of interest.
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Received February 20, 2011
Accepted April 26, 2011
articles This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
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Green synthesis of gold nanostructures using pear extract as effective reducing and coordinating agent

Department of Environmental Engineering, Kyungpook National University, 80 Daehak-ro, Buk-gu, Daegu 702-701, Korea
daesung@knu.ac.kr
Korean Journal of Chemical Engineering, December 2011, 28(12), 2329-2335(7), 10.1007/s11814-011-0115-4
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Abstract

Biosynthesis of gold nanoparticles and nanoplates (GNPs) was accomplished using aqueous fractions of pear extract as a safe, reducing, particle-stabilizing, and shape-directing agent. The maximum yields of spherical gold nanoparticles having the average sizes of 40, 20, and 10 nm were achieved at 30, 60, and 90℃ , respectively, at a pear extract concentration of 45% (v/v). The maximum yield of gold nanoplates was obtained with sizes ranging from 20 to 400 nm, particularly at reaction temperatures of 30, 60, and 90℃ , at a pear extract concentration of 5% (v/v). The surface chemistry analysis of the GNPs suggests that the sugars and peptides or proteins as key biomolecules of the pear extract play a crucial role in the reduction of Au(III), subsequently resulting in healthy capping. Therefore, this environmentally friendly synthesis method of GNPs for the particular type of morphologies is expected to be a competitive_x000D_ alternative to existing physical and chemical methods.

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