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Received May 25, 2009
Accepted September 16, 2009
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Hybrid supercapacitor based on poly(aniline-co-m-anilicacid) and activated carbon in non-aqueous electrolyte
Department of Chemistry, Manipal Institute of Technology, Manipal 576104, India 1Central Electrochemical Research Institute, Karaikudi 630006, India
chemselva78@gmail.com
Korean Journal of Chemical Engineering, March 2010, 27(3), 977-982(6), 10.1007/s11814-010-0120-z
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Abstract
A hybrid asymmetrical super capacitor has been fabricated based on p-doped poly(aniline-co-m-anilicacid) and activated carbon coated on SS electrodes. The characterization of material, electrode and performance of the super capacitor has been studied by FTIR, Cyclic Voltammetry, TGA/DTA, AC Impedance spectroscopy, and galvanostatic charge-discharge tests. The super capacitor showed a maximum specific capacitance of 102 F/g at a scan rate of 10 mV/s. The normalized active-reactive power behavior of the capacitor has been determined. The time constant calculated for the super capacitor is 6 milliseconds, indicating the suitability of the system for efficient use at low frequency range.
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References
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Wang XH, Wang LX, Jing XP, Wang FS, Synth. Met., 69, 335 (1995)
Ranger M, Leclerc M, Synth. Met., 84, 85 (1997)
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Ryu K, Kim K, Park N, Park Y, Chang S, J. Power Sources, 103, 305 (2002)
Park JH, Park OO, J. Power Sources, 111(1), 185 (2002)
Hatchett DW, Josowicz M, Janata J, J. Electrochem. Soc., 146(12), 4535 (1999)
Ryu KS, Kim KM, Park NG, Park YJ, Chang SH, J. Power Sources, 103(2), 305 (2002)
Clemente A, Panero S, Spila E, Scrosati B, Solid State Ion., 85(1-4), 273 (1996)
Arbizzani C, Mastragostino M, Soavi F, J. Power Sources, 100(1-2), 164 (2001)
Ryu KS, Lee YG, Hong YS, Park YJ, Wu XL, Kim KM, Kang MG, Park NG, Chang SH, Electrochim. Acta, 50(2-3), 843 (2004)
Seo KI, Chung IJ, Polym., 41, 4491 (2004)
Tranvan F, Garreau S, Louarn G, Froyer G, Chevrot C, J.Mater Chem., 11, 1378 (2001)
Hatchett DW, Josowicz M, Janata J, J. Electrochem. Soc., 146(12), 4535 (1999)
Wei Y, Hsueh KF, J. Polym. Sci., 27, 4351 (1989)
Ansari R, Price WE, Wallace GG, React. Funct. Polym., 56, 141 (2003)
Hagiwara T,Yamaura M, Iwata K, Synth. Met., 25, 243 (1988)
B. E. Conway, Electrochemical Supercapacitors: Scientific Fundamentals and Technological Applications, Kluwer Academic Publishers, Plenum press, New York (1999)
Qu DY, Shi H, J. Power Sources, 74(1), 99 (1998)
Song HK, Jung YH, Lee KH, Dao LH, Electrochim. Acta, 44(20), 3513 (1999)
Keiser H, Beccu KD, Gutjahr MA, Electrochim Acta., 12, 539 (1976)
Taberna PL, Simon P, Fauvarque JF, J. Electrochem. Soc., 150(3), A292 (2003)
Zheng JP, Huang J, Jow TR, J. Electrochem. Soc., 144(6), 2026 (1997)
