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Received September 16, 2009
Accepted November 23, 2009
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Catalytic decomposition of nitrous oxide over Fe-BEA zeolites: Essential components of iron active sites
School of Applied Chemical Engineering and The Research Institute for Catalysis, Chonnam National University, Youngbong-dong 300, Gwangju 500-757, Korea 1Department of Chemical Engineering, Chungbuk National University, Cheongju, Chungbuk 361-763, Korea 2Electrochemical Reaction and Technology Laboratory (ERTL), Department of Environmental Science and Engineering, GIST, Oryong-dong 1, Gwangju 500-712, Korea
gseo@chonnam.ac.kr
Korean Journal of Chemical Engineering, January 2010, 27(1), 76-82(7)
https://doi.org/10.1007/s11814-010-0099-5
https://doi.org/10.1007/s11814-010-0099-5
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Abstract
The catalytic decomposition of N2O was investigated over Fe-BEA zeolites treated with various methods such as reduction, steaming and dissolution with potassium nitrate and nitric acid solutions in order to deduce the essential components of the active sites for the decomposition. The iron species were characterized by XPS, XANES, ESR, NO adsorption, and linear sweep voltammetry. The reduction-treated Fe-BEA zeolite with the large amounts of Fe(II) and Fe(III) species showed the highest activity. On the contrary, the dissolution treatment with the potassium nitrate solution seriously deteriorated the catalytic activity of the Fe-BEA zeolite by agglomerating iron oxide clusters and interaction between iron and potassium atoms. The catalytic roles of Fe(II)/Fe(III) species and the negative effect of potassium on the catalytic activity of the Fe-BEA zeolites were discussed.
References
Perez-Ramirez J, Appl. Catal. B: Environ., 70(1-4), 31 (2007)
Kapteijn F, Rodriguezmirasol J, Moulijn JA, Appl. Catal. B: Environ., 9(1-4), 25 (1996)
Centi G, Perathoner S, Vazzana F, Marella M, Tomaselli M, Mantegazza M, Adv. Environ. Res., 4, 325 (2000)
Ates A, Appl. Catal. B: Environ., 76(3-4), 282 (2007)
Guzman-Vargas A, Delahay G, Coq B, Appl. Catal. B: Environ., 42(4), 369 (2003)
Boissel V, Tahir S, Koh CA, Appl. Catal. B: Environ., 64(3-4), 234 (2006)
Kondratenko EV, Perez-Ramirez J, Appl. Catal. B: Environ., 64(1-2), 35 (2006)
Jisa K, Novakova J, Schwarze M, Vondrova A, Sklenak S, Sobalik Z, J. Catal., 262(1), 27 (2009)
Roy PK, Prins R, Pirngruber GD, Appl. Catal. B: Environ., 80(3-4), 226 (2008)
Dzwigaj S, Janas J, Rojek W, Stievano L, Wagner FE, Averseng F, Che M, Appl. Catal. B: Environ., 86(1-2), 45 (2009)
Oygarden AH, Perez-Ramirez J, Appl. Catal. B: Environ., 65(1-2), 163 (2006)
Perez-Ramirez J, Groen JC, Bruckner A, Kumar MS, Bentrup U, Debbagh MN, Villaescusa LA, J. Catal., 232(2), 318 (2005)
Zecchina A, Rivallan M, Berlier G, Lamberti C, Ricchiardi G, Phys. Chem. Chem. Phys., 9, 3483 (2007)
Dubkov KA, Ovanesyan NS, Shteinman AA, Starokon EV, Panov GI, J. Catal., 207(2), 341 (2002)
Berrier E, Ovsitser O, Kondratenko EV, Schwidder M, Grunert W, Bruckner A, J. Catal., 249(1), 67 (2007)
Kaucky D, Sobalik Z, Schwarze M, Vondrova A, Wichterlova B, J. Catal., 238(2), 293 (2006)
Hensen EJM, Zhu Q, Janssen RAJ, Magusin PCMM, Kooyman PJ, van Santen RA, J. Catal., 233(1), 123 (2005)
Centi G, Perathoner S, Arrigo R, Giordano G, Katovic A, Pedula V, Appl. Catal. A: Gen., 307(1), 30 (2006)
Perez-Ramirez J, Kapteijn F, Groen JC, Domenech A, Mul G, Moulijn JA, J. Catal., 214(1), 33 (2003)
Sankar G, Shiju NR, Watts ID, Nikitenko S, Bars W, Res. Chem. Intermed., 34, 649 (2008)
Choi SH, Wood BR, Ryder JA, Bell AT, J. Phys. Chem. B, 107(43), 11843 (2003)
Choi JS, Youn HK, Kwak BH, Wang Q, Yang KS, Chung JS, Appl. Catal. B: Environ., 91(1-2), 210 (2009)
Schwidder M, Kumar MS, Klementiev K, Pohl MM, Bruckner A, Grunert W, J. Catal., 231(2), 314 (2005)
Perez-Ramirez J, Kumar MS, Bruckner A, J. Catal., 223(1), 13 (2004)
Schwidder M, Grunert W, Bentrup U, Bruckner A, J. Catal., 239(1), 173 (2006)
Yuranov I, Bulushev DA, Renken A, Kiwi-Minsker L, Appl. Catal. A: Gen., 319, 128 (2007)
Chaki T, Arai M, Ebina T, Shimokawabe M, J. Catal., 218(1), 220 (2003)
Capek L, Kreibich V, Dedecek J, Grygar T, Wichterlova B, Sobalik Z, Martens JA, Brosius R, Tokarova V, Microporous Mesoporous Mat., 80, 279 (2005)
Jia JF, Wen B, Sachtler WMH, J. Catal., 210(2), 453 (2002)
Rivallan M, Ricchiardi G, Bordiga S, Zecchina A, J. Catal., 264(2), 104 (2009)
Kapteijn F, Rodriguezmirasol J, Moulijn JA, Appl. Catal. B: Environ., 9(1-4), 25 (1996)
Centi G, Perathoner S, Vazzana F, Marella M, Tomaselli M, Mantegazza M, Adv. Environ. Res., 4, 325 (2000)
Ates A, Appl. Catal. B: Environ., 76(3-4), 282 (2007)
Guzman-Vargas A, Delahay G, Coq B, Appl. Catal. B: Environ., 42(4), 369 (2003)
Boissel V, Tahir S, Koh CA, Appl. Catal. B: Environ., 64(3-4), 234 (2006)
Kondratenko EV, Perez-Ramirez J, Appl. Catal. B: Environ., 64(1-2), 35 (2006)
Jisa K, Novakova J, Schwarze M, Vondrova A, Sklenak S, Sobalik Z, J. Catal., 262(1), 27 (2009)
Roy PK, Prins R, Pirngruber GD, Appl. Catal. B: Environ., 80(3-4), 226 (2008)
Dzwigaj S, Janas J, Rojek W, Stievano L, Wagner FE, Averseng F, Che M, Appl. Catal. B: Environ., 86(1-2), 45 (2009)
Oygarden AH, Perez-Ramirez J, Appl. Catal. B: Environ., 65(1-2), 163 (2006)
Perez-Ramirez J, Groen JC, Bruckner A, Kumar MS, Bentrup U, Debbagh MN, Villaescusa LA, J. Catal., 232(2), 318 (2005)
Zecchina A, Rivallan M, Berlier G, Lamberti C, Ricchiardi G, Phys. Chem. Chem. Phys., 9, 3483 (2007)
Dubkov KA, Ovanesyan NS, Shteinman AA, Starokon EV, Panov GI, J. Catal., 207(2), 341 (2002)
Berrier E, Ovsitser O, Kondratenko EV, Schwidder M, Grunert W, Bruckner A, J. Catal., 249(1), 67 (2007)
Kaucky D, Sobalik Z, Schwarze M, Vondrova A, Wichterlova B, J. Catal., 238(2), 293 (2006)
Hensen EJM, Zhu Q, Janssen RAJ, Magusin PCMM, Kooyman PJ, van Santen RA, J. Catal., 233(1), 123 (2005)
Centi G, Perathoner S, Arrigo R, Giordano G, Katovic A, Pedula V, Appl. Catal. A: Gen., 307(1), 30 (2006)
Perez-Ramirez J, Kapteijn F, Groen JC, Domenech A, Mul G, Moulijn JA, J. Catal., 214(1), 33 (2003)
Sankar G, Shiju NR, Watts ID, Nikitenko S, Bars W, Res. Chem. Intermed., 34, 649 (2008)
Choi SH, Wood BR, Ryder JA, Bell AT, J. Phys. Chem. B, 107(43), 11843 (2003)
Choi JS, Youn HK, Kwak BH, Wang Q, Yang KS, Chung JS, Appl. Catal. B: Environ., 91(1-2), 210 (2009)
Schwidder M, Kumar MS, Klementiev K, Pohl MM, Bruckner A, Grunert W, J. Catal., 231(2), 314 (2005)
Perez-Ramirez J, Kumar MS, Bruckner A, J. Catal., 223(1), 13 (2004)
Schwidder M, Grunert W, Bentrup U, Bruckner A, J. Catal., 239(1), 173 (2006)
Yuranov I, Bulushev DA, Renken A, Kiwi-Minsker L, Appl. Catal. A: Gen., 319, 128 (2007)
Chaki T, Arai M, Ebina T, Shimokawabe M, J. Catal., 218(1), 220 (2003)
Capek L, Kreibich V, Dedecek J, Grygar T, Wichterlova B, Sobalik Z, Martens JA, Brosius R, Tokarova V, Microporous Mesoporous Mat., 80, 279 (2005)
Jia JF, Wen B, Sachtler WMH, J. Catal., 210(2), 453 (2002)
Rivallan M, Ricchiardi G, Bordiga S, Zecchina A, J. Catal., 264(2), 104 (2009)
