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Received October 11, 2007
Accepted January 5, 2008
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Effect of cocatalyst and carbon dioxide pressure on the synthesis of polycarbonate from phenyl glycidyl ether and carbon dioxide
Division of Chemical Engineering, Pusan National University, Busan 609-735, Korea
dwpark@pusan.ac.kr
Korean Journal of Chemical Engineering, July 2008, 25(4), 693-696(4)
https://doi.org/10.1007/s11814-008-0113-3
https://doi.org/10.1007/s11814-008-0113-3
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Abstract
The copolymerization of phenyl glycidyl ether (PGE) and carbon dioxide was performed in the presence of ionic liquid catalyst. 1-Butyl-3-methyl imidazolium chloride, tetrabutylamouim chloride and 1-n-butylpyridinium chloride were used as catalyst for this reaction carried out in a batch reactor. All the ionic liquid catalysts showed good catalytic activity for the synthesis of polycarbonates with very low polydispersity, close to 1. The carbonate content, turnover number (TON), and average molecular weight of the copolymer were affected by the structure of the ionic liquid. High carbon dioxide pressure enhanced TON and carbonate content because of the increase of carbon dioxide absorption in PGE solution. ZnBr2 and a Zn-Co cyanide complex were also tested as a catalyst and/or cocatalyst for this reaction to compare their catalytic performance with the imidazolium salt ionic liquids.
References
Peppel WJ, Ind. Eng. Chem., 50, 767 (1958)
Inoue S, Yamazaki N, Organic and bioorganic chemistry of carbon dioxide, Kodansha Ltd., Tokyo (1981)
Inoue S, Tsuruta T, Koinuma H, J. Polym. Sci. Polym. Lett., 7, 287 (1969)
Rokicki A, Kuran WJ, Macromol. Sci. Rev. Macromol. Chem., C21, 135 (1981)
Super MS, Beckman EJ, Trends Polym. Sci., 5(7), 236 (1997)
Darensbourg DJ, Mackiewiicz RM, Phelps AL, Billodeaux DR, Accounts Chem. Res., 37, 836 (2004)
Coates GW, Moore DR, Angew. Chem.-Int. Edit., 43, 6618 (2004)
Sugimoto H, Inoue S, J. Polym. Sci. A: Polym. Chem., 42(22), 5561 (2004)
Kuran W, Listos T, Macromol. Chem. Phys., 195, 1011 (1994)
Kihara N, Hara N, Endo T, J. Org. Chem., 58, 6198 (1993)
Nishikubo T, Kameyama A, Yamashita J, Fukumitsu T, Maejima C, Tomoi M, J. Polym. Sci. A: Polym. Chem., 33(7), 1011 (1995)
Yu BS, Jeong ES, Kim KH, Park DW, Park SW, Lee JW, React. Kinet. Catal. Lett., 84(1), 175 (2005)
Guo JT, Wang XY, Xu YS, Sun JW, J. Appl. Polym. Sci., 87, 2350 (2003)
Billard I, Moutiers G, Labet A, Azzi AE, Gaillard C, Mariet C, Lutzenkirchen K, Inorg. Chem., 42(5), 1726 (2003)
Olivier-Bourbigou H, Magna L, J. Mol. Catal. A-Chem., 182, 419 (2002)
Song CE, Shim WH, Roh EJ, Choi JH, Chem. Commun., 1695 (2000)
Kim DS, Ahn WS, Korean J. Chem. Eng., 20(1), 39 (2003)
Lee EH, Cha SW, Dharma MM, Choe Y, Ahn JY, Park DW, Korean J. Chem. Eng., 24(3), 547 (2007)
Mun NY, Kim KH, Park DW, Choe Y, Kim I, Korean J. Chem. Eng., 22(4), 556 (2005)
Park DW, Mun NY, Lee EH, Choe Y, Park SW, React. Kinet. Catal. Lett., 89(1), 149 (2006)
Kim I, Yi MJ, Pyun SH, Park DW, Ha CS, Stud. Surf. Sci. Catal., 153, 239 (2004)
Chen XH, Shen ZQ, Zhang YF, Macromolecules, 24, 5305 (1991)
Tan CS, Hsu TJ, Macromolecules, 30(11), 3147 (1997)
Sun J, Fujita SI, Zhao F, Arai M, Green Chem., 6, 613 (2004)
Fuwei L, Linfei X, Chungu X, Bin H, Tetrahedron Lett., 45, 8307 (2004)
Inoue S, Yamazaki N, Organic and bioorganic chemistry of carbon dioxide, Kodansha Ltd., Tokyo (1981)
Inoue S, Tsuruta T, Koinuma H, J. Polym. Sci. Polym. Lett., 7, 287 (1969)
Rokicki A, Kuran WJ, Macromol. Sci. Rev. Macromol. Chem., C21, 135 (1981)
Super MS, Beckman EJ, Trends Polym. Sci., 5(7), 236 (1997)
Darensbourg DJ, Mackiewiicz RM, Phelps AL, Billodeaux DR, Accounts Chem. Res., 37, 836 (2004)
Coates GW, Moore DR, Angew. Chem.-Int. Edit., 43, 6618 (2004)
Sugimoto H, Inoue S, J. Polym. Sci. A: Polym. Chem., 42(22), 5561 (2004)
Kuran W, Listos T, Macromol. Chem. Phys., 195, 1011 (1994)
Kihara N, Hara N, Endo T, J. Org. Chem., 58, 6198 (1993)
Nishikubo T, Kameyama A, Yamashita J, Fukumitsu T, Maejima C, Tomoi M, J. Polym. Sci. A: Polym. Chem., 33(7), 1011 (1995)
Yu BS, Jeong ES, Kim KH, Park DW, Park SW, Lee JW, React. Kinet. Catal. Lett., 84(1), 175 (2005)
Guo JT, Wang XY, Xu YS, Sun JW, J. Appl. Polym. Sci., 87, 2350 (2003)
Billard I, Moutiers G, Labet A, Azzi AE, Gaillard C, Mariet C, Lutzenkirchen K, Inorg. Chem., 42(5), 1726 (2003)
Olivier-Bourbigou H, Magna L, J. Mol. Catal. A-Chem., 182, 419 (2002)
Song CE, Shim WH, Roh EJ, Choi JH, Chem. Commun., 1695 (2000)
Kim DS, Ahn WS, Korean J. Chem. Eng., 20(1), 39 (2003)
Lee EH, Cha SW, Dharma MM, Choe Y, Ahn JY, Park DW, Korean J. Chem. Eng., 24(3), 547 (2007)
Mun NY, Kim KH, Park DW, Choe Y, Kim I, Korean J. Chem. Eng., 22(4), 556 (2005)
Park DW, Mun NY, Lee EH, Choe Y, Park SW, React. Kinet. Catal. Lett., 89(1), 149 (2006)
Kim I, Yi MJ, Pyun SH, Park DW, Ha CS, Stud. Surf. Sci. Catal., 153, 239 (2004)
Chen XH, Shen ZQ, Zhang YF, Macromolecules, 24, 5305 (1991)
Tan CS, Hsu TJ, Macromolecules, 30(11), 3147 (1997)
Sun J, Fujita SI, Zhao F, Arai M, Green Chem., 6, 613 (2004)
Fuwei L, Linfei X, Chungu X, Bin H, Tetrahedron Lett., 45, 8307 (2004)
