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Received August 14, 2007
Accepted October 7, 2007
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This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
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One-step synthesis of methylmethacrylate from methacrolein over Keggin-type heteropoly compounds
State Key Laboratory Chemical Resource Engineering, Beijing University of Chemical Technology, Box35# Beijing, 100029, China
xiajunguo@sohu.com
Korean Journal of Chemical Engineering, July 2008, 25(4), 675-680(6), 10.1007/s11814-008-0111-5
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Abstract
One-step synthesis of methylmethacrylate (MMA) using heteropoly compounds (HPCs) as catalysts was demonstrated by feeding a mixture of methacrolein (MAL), air, water, nitrogen and MeOH (methanol). The HPCs with different counter-ions, such as H1.7Cs1.5Cu0.25As0.1PMo11VO40 (CsPMo11VO40), H1.7La0.7Cu0.25As0.1PMo11VO40 (LaPMo11VO40) and H1.7K1.5Cu0.25As0.1PMo11VO40 (KPMo11VO40), were studied in oxidation of MAL, esterification of methacrylic acid (MAA) and one-step synthesis of MMA from MAL, respectively. The selectivity of MAA was up to 45.7% and MMA was 44.6% with 93.3% MAL conversion over CsPMo11VO40.
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References
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Tsigdinos GA, Hallada CJ, Inorg. Chem., 7, 437 (1968)
Enbo W, Changlin H, Lin X, Introduction of polyoxometalates chemistry, Chemical Industry Press, Beiing (1998)
Rocchiccioli-Deltcheff C, Fournier M, Franck R, Thouvenot R, Inorg. Chem., 22, 207 (1983)
Mizuno N, Suh DJ, Han W, Kudo T, J. Mol. Catal. A-Chem., 114, 309 (1996)
Inumaru K, Ono A, Kubo H, Misono M, Fara. Trans., 94, 6 (1998)
Langpape M, Millet JMM, Ozkan US, Boudeulle M, J. Catal., 181(1), 80 (1999)
Dimitratos N, Vedrine JC, Appl. Catal. A: Gen., 256(1-2), 251 (2003)
Mizuno N, Misono M, Chem. Rev., 98(1), 199 (1998)
Kozhevnikov IV, Catalysis by polyoxometalates (catalysis for fine chemical synthesis), Chemical Industry Press, Beiing (2005)
Selli E, Forni L, Microporous Mesoporous Mater., 31, 129 (1999)
Thomas R, van Oers EM, de Beer VHJ, Medema J, Moulijn JA, J. Catal., 76, 241 (1982)
Song IK, Kim HS, Chun MS, Korean J. Chem. Eng., 20(5), 844 (2003)
Cabello CI, Cabrerizo FM, Alvarez A, Thomas HJ, J. Mol. Catal. A-Chem., 186, 89 (2002)
Deng Q, Jiang S, Cai T, Peng Z, Fang Z, J. Mol. Catal. A-Chem., 229, 165 (2005)
Kozhevnikov IV, Chem. Rev., 98(1), 171 (1998)
Chi HP, Cui YH, Wang ZL, Chinese Patent CN 1052848A
Li W, Oshihara K, Ueda W, Appl. Catal. A: Gen., 182(2), 357 (1999)
Holles JH, Dillon CJ, Labinger JA, Davis ME, J. Catal., 218(1), 42 (2003)
Landi G, Lisi L, Volta JC, J. Mol. Catal. A-Chem., 222(1-2), 75 (2004)
Lin MH, Desai TB, Kaiser FW, Klugherz PD, Catal. Today, 61(1-4), 223 (2000)
Zhu B, Li HB, Yang WS, Lin LW, Catal. Today, 93, 229 (2004)
