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Received January 10, 2006
Accepted March 1, 2007
articles This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
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Nonlinear model based control of two-product reactive distillation column

Department of Chemical & Biological Engineering, Chungnam National University, 220, Gung-dong, Yousung, Daejeon 305-764, Korea 1Department of Chemical & Biological Engineering, University of Colorado, Boulder, CO 80309-0424, USA
mwhan@cnu.ac.kr
Korean Journal of Chemical Engineering, July 2006, 23(4), 540-546(7), 10.1007/BF02706791
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Abstract

Nonlinear feedback control scheme for reactive distillation column has been proposed. The proposed control scheme is derived in the framework of Nonlinear Internal Model Control. The product compositions and liquid and vapor flow rates in sections of the reactive distillation column are estimated from selected tray temperature measurements by an observer. The control scheme is applied to an example reactive distillation column in which two products are produced in a single column and the reversible reaction A+B=C+D occurs. The relative volatilities are favorable for reactive distillation so that the reactants are intermediate boilers between the light product C and the heavy product D. Ideal physical properties, kinetics, and vapor-liquid equilibrium are also assumed. It is shown that the proposed control scheme keeps tight product composition control.

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