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Issue
Korean Journal of Chemical Engineering,
Vol.36, No.1, 101-108, 2019
Adsorption and precipitation of anionic dye Reactive Red 120 from aqueous solution by aminopropyl functionalized magnesium phyllosilicate
Kim YW, Kim JH, Moon DH, Shin HJ
Dye wastewater causing destruction in ecosystem from a variety of plants an operation needs various factors for environmental cleanup. To improve removal efficiency of dye wastewater, various adsorbents including clay and nonclay-related materials have been tried. The use of soluble aminopropyl functionalized magnesium phyllosilicate (Mg-AMP clay) as an adsorbent for the textile anionic dye Reactive Red 120 (RR 120) was examined thermodynamically and kinetically. The adsorption kinetics followed the pseudo-second-order and Langmuir isotherm equation fitted best models. A maximum amount of adsorption was determined to be 229.9mg/g, which is one of the highest values studied so far. An Mg-AMP clay dosage of 10mg/mL obtained from Langmuir model a maximum adsorption capacity of 229.94, 182.26 and 156.54mg/g at 298.15, 308.15 and 318.15 K, respectively. Moreover the thermodynamic activation parameters such as enthalpy and entropy were determined. We suggest the removal mechanism of RR 120 using Mg-AMP clay by adsorption and precipitation.
Keywords: Anionic Dyes; Magnesium Phyllosilicate; Clay; Adsorption; Precipitation; Reactive Red 120
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[Cited By]
  1. Ying TY, Raman AAA, Bello MM, Buthiyappan A, Korean Journal of Chemical Engineering, 37(12), 2179, 2020
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