| Issue |
Korean Chemical Engineering Research,
Vol.50, No.4, 729-732, 2012
Vol.50, No.4, 729-732, 2012
다중벽 탄소나노튜브와 다양한 나노입자 복합체의 In-situ 합성법개발 및 구조제어연구
Study about the In-situ Synthesis and Structure Control of Multi-walled Carbon Nanotubes and their Nanocomposites
본 논문에서 이온성액체를 이용한 초음파화학을 통해서 칼코젠 나노입자를 in-situ로 합성하여서 다중벽 탄소나노튜브(MWCNT) 위에 도포하였다. 1-Butyl-3-methylimidazolium tetrafluoroborate (BMimBF4) 이온성액체를 이용해서 MWCNT의 표면을 기능화하였다. 합성된 MWCNT/BMimBF4/CdTe, MWCNT/BMimBF4/ZnTe, MWCNT/BMimBF4/ZnSe 나노복합체를 TEM과 EDS를 이용해서 분석하였다. 특히, MWCNT/BMimBF4/CdTe, MWCNT/BMimBF4/ZnTe, and MWCNT/BMimBF4/ZnSe 나노복합체는 각각 요철과 같거나, 거칠거나 부드러운 코어-쉘 형태와 같은 특이한 구조를 보여주었다. 본 연구는 반응속도가 다른 전구체로부터 얻어진 이성분 반도체 나노입자를 합성과 동시에 탄소나노튜브에 도포할 수 있는 새로운 합성법을 제시한다.
Herein we report the in-situ synthesis and direct decoration of chalcogenide naoparticles (NPs) onto multiwalled carbon nanotubes (MWCNTs) through an ionic liquid-assisted sonochemical method (ILASM). The as-obtained MWCNT/BMimBF4/CdTe, MWCNT/BMimBF4/ZnTe and MWCNT/BMimBF4/ZnSe nanocomposites were characterized by TEM images and EDS spectra. In particular, the morphologies of nanocomposites such as bump-like, rough, and smooth core-shell structures were strongly influenced by the type of precursors and the interactions with MWCNT. This synthetic strategy opens a new way to directly synthesize and deposit semiconducting NPs (s-NPs) onto CNTs, which consist of binary components obtained from two precursors with different reaction rates.
[References]
- Wildgoose GG, Banks CE, Compton RG, Small., 2, 182, 2006
- Eder D, Chem. Rev., 110(3), 1348, 2010
- Park HS, Choi BG, Yang SH, Shin WH, Kang JK, Jung D, Hong WH, Small., 5, 1754, 2009
- Park HS, Kim JS, Choi, BG, Jo SM, Kim DY, Hong WH, Jang SY, Carbon., 48, 1325, 2010
- Peng X, Chen J, Misewich JA, Wong SS, Chem. Soc. Rev., 38, 1076, 2009
- Cho N, Choudhury KR, Thapa RB, Sahoo Y, Ohulchanskyy T, Cartwright AN, Lee KS, Prasad PN, Adv. Mater., 19(2), 232, 2007
- Robel I, Bunker BA, Kamat PV, Adv. Mater., 17(20), 2458, 2005
- Guo Y, Shi DL, Cho HS, Dong ZY, Kulkarni A, Pauletti GM, Wang W, Lian J, Liu W, Ren L, Zhang QQ, Liu GK, Huth C, Wang LM, Ewing RC, Adv. Funct. Mater., 18(17), 2489, 2008
- Fukushima T, Kosaka A, Ishimura Y, Yamamoto T, Takigawa T, Ishii N, Aida T, Science., 300, 2072, 2003
- Suslick KS, Ultrasound: Its Chemical, Physical and Biological Effects, VCH, Weinheim, Germany, 1988
- Fukushima T, Aida T, Chem. Eur. J., 13, 5048, 2007
- Choi BG, Park HS, Park TJ, Kim DH, Lee SY, Hong WH, Electrochem. Commun., 11, 672, 2009
- Gu F, Li CZ, Wang SF, Inorg. Chem., 46(13), 5343, 2007
[Cited By]
참고문헌정보(참고문헌, 인용문헌)는 화학공학소재연구정보센터에 의해 제공되고 있습니다.