| Issue |
Korean Chemical Engineering Research,
Vol.49, No.3, 301-305, 2011
Vol.49, No.3, 301-305, 2011
ABS/실리케이트 복합체의 제조 및 열적특성 연구
Study on Fabrication and Thermal Properties of the ABS/silicate Composites
ABS/실리케이트 복합체를 clay의 종류 및 함량을 변화시키며 에멀젼 중합을 이용하여 제조하였다. ABS의 화학구조는 적외선분광기(FT-IR)를 이용하여 이중결합 C-H 신축진동 피크(3000 cm^(-1) 근처)의 변화를 통해 확인하였다. ABS/실리케이트 복합체의 열적특성은 시차주사열용량분석기(DSC) 와 열중량분석기(TGA)를 이용하여 관찰하였다. Clay의 종류에 따른 ABS의 유리전이온도에는 큰 변화가 나타나지 않음을 알 수 있었다. TGA에 의한 분해온도는 20A의 함량이 3 wt%인 ABS/20A 복합체에서 가장 높은 값을 나타내었다. 복합체의 실리케이트 분산정도는 X-선회절(XRD)법을 이용하여 측정하였다. ABS/20A 복합체의 실리케이트 분산은 20A 함량에 의존하였고, 함량이 5 wt% 이상 첨가되었을 때 20A의 회절 피크가 나타나는 것을 확인하였다.
ABS/silicate composites with different clay types and compositions were prepared by in situ emulsion polymerization. The chemical structure of ABS was confirmed by the change of C-H stretching peak(near 3000 cm^(-1)) in fourier transform-infrared(FT-IR) spectrum. The thermal properties of the ABS/silicate composites were investigated by differential scanning calorimetry(DSC) and thermogravimetric analyzer(TGA). There was no distinct change in glass transition temperature of the ABS/silicate composites with different clay types. TGA curve indicates a dramatic increase in degradation temperature in case of ABS/20A composite with 3 wt% 20A. The silicate dispersion in the composites was measured by X-ray diffraction(XRD). The silicate dispersion in ABS/20A composites depended on the 20A composition. XRD results showed that the diffraction peak of the ABS/20A composite appeared when the content of 20A was higher than 5 wt%.
[References]
- Nam PH, Maiti P, Okamoto M, Kotaka T, Hasegawa N, Usuki A, Polymer, “A Hierarchical Structure and Properties of Intercalated Polypropylene/clay Nanocomposites", 42(23), 9633, 2001
- Zheng L, Farris RJ, Coughlin EB, Macromolecules, “Novel Polyofefin Nanocomposites: Synthesis and Characterizations of Metallocenecatalyzed Polyolefin Polyhedral Oligomeric Silsesquioxane Copolymers", 34(23), 8034, 2001
- Liu XH, Wu QJ, Polymer, “PP/clay Nanocomposites Prepared by Grafting-melt Intercalation", 42(25), 10013, 2001
- Lele A, Mackley M, Galgali G, Ramesh C, J. Rheol., “In Situ Rheox-ray Investigation of Flow-induced Orientation in Layered Silicate-syndiotatic Polypropylene Nanocomposite melt", 46(5), 1091, 2002
- Li J, Zhou C, Gang W, Polym. Test., “Study on Nonisothermal Crystallization of Maleic Anhydride Grafted Polypropylene/montmorillonite Nanocomposite", 22, 217, 2003
- Kim YC, Polym. J., “Effect of Maleated Polyethylene on the Crystallization Behavior of LLDPE/clay Nanocomposites", 38, 250, 2006
- Cho MS, Lee YK, Polymer(Korea)., “Polymer Nanocomposites Using Nano Clay", 27, 31, 2006
- Choi YS, Chung IJ, Korean Chem. Eng. Res., “Comprehending Polymer-Clay Nanocomposites and Their Future Works", 46(1), 23, 2008
- Kulich DM, Kelly PD, Pace JE, “Encyclopedia of Polymer Science and Engineering" John Wiley and Sons, New York, 1985
- Rubin II, “Hand book of Plastic Materials and Technology" Wiley, New York, 1990
- Ro YC, Choi SO, Lee JH, Name KD, HWAHAK KONGHAK, “Nickel Plating Techniques of Blend of ABS-PC Engineering Plastics", 34(6), 683, 1996
- Jang LW, Kang CM, Lee DC, J. Polym. Sci. B: Polym. Phys., “A New Hybrid Nanocomposite Prepared by Emulsion Copolymerization of ABS in the Presence of Clay", 39(6), 719, 2001
- Choi YS, Xu MZ, Chung IJ, Polymer, “Synthesis of Exfoliated Acrylonitrile-butadiene-styrene Copolymer (ABS) Clay Nanocomposites: Role of Clay as a Colloidal Stabilizer", 46(2), 531, 2005
- Modesti M, Besco S, Lorenzetti A, Causin V, Marega C, Gilman JW, Fox DN, Trulove PC, De Long HC, Zammarano M, Macromolecules., “ABS/clay Nanocomposites Obtained by a Solution Technique: Influenece of Clay Organic Modifiers", 2209, 2007
- Pourabas B, Raeesi V, Polymer, “Preparation of ABS/montmorillonite Nanocomposite Using a Solvent/non-solvent Method", 46(15), 5533, 2005
- Kim JH, Study on Synthesis of Polymer/Layered Silicate Nanocomposites using Reactive Amphiphiles and their Characterization, Ph.D thesis, KAIST, 2007
- Kim JH, Kim K, Kim YC, Chung IJ, Polymer J., “Effect of Reactive Amphiphiles on the Silicate Dispersion and Degradation Behavior of ABS/layered Silicate Nanocomposites", 40, 268, 2008
- Wang S, Hu Y, Song L, Wang Z, Chen Z, Fan W, Polymer Degradation Stability., “Preparation and Thermal Properties of ABS/montmorillonite Nanocomposite", 77, 423, 2002
- Lim SK, Hong EP, Song YH, Park BJ, Choi HJ, Chin IJ, Polym. Eng. Sci., “Preparation and Interaction Characteristics of Exfoliated ABS/Organoclay Nanocomposite", 50(3), 504, 2010
참고문헌정보(참고문헌, 인용문헌)는 화학공학소재연구정보센터에 의해 제공되고 있습니다.