Issue
Korean Chemical Engineering Research,
Vol.48, No.2, 129-139, 2010
분류층 습식 석탄가스화 기술
Entrained-Flow Coal Water Slurry Gasification
석탄으로부터 수소, 일산화탄소 등의 가스 연료를 생산하기 위하여 개발된 석탄 가스화 공정은 이산화탄소 저장, 환경 유해 물질 저감 등의 우수성으로 인하여 최근 세계 각국에서 앞다투어 개발에 나서고 있다. 75 μm 이하의 미분탄을 이용하는 분류층 가스화 공정은 용량의 대형화가 쉽고, 에너지 전환 효율이 우수하여 석탄가스화복합발전(IGCC) 등에 널리 이용되고 있다. 특히 석탄슬러리를 원료로 사용하는 습식 분류층 가스화 공정은 기술적으로 성숙되어 가장 많이 보급되고 있다. 본 논문에서는 습식 분류층 가스화 공정을 이루는 석탄전처리, 버너, 가스화기, 슬래그용융, 가스화 운전 특성과 설계 및 해석을 위한 수치모사 등의 요소기술 개발 현황을 고찰하였다. 습식 석탄가스화는 IGCC 플랜트에서 뿐만 아니라 합성석유, SNG, 화학원료 제조용으로 활용될 수 있으며 융합 공정, 연료 다변화 등에 대응하기 위하여 요소기술별 추가적인 기술개발이 이루어져야 할 것으로 판단된다.
Coal gasification process, which had developed originally to convert coal from hydrogen and carbon monoxide, has used and developed in many countries because of environmental advantages such as carbon dioxide storage, decrease of pollutants and so on. Generally entrained-flow gasification process using pulverized coal under 75 μm is used in Integrated Gas Combined Cycle(IGCC) because of easy scale up and high efficiency of energy conversion. Especially entrained-flow gasifers with coal water slurry have been used in many applications due to its fully developed technologies. In this paper, several technologies for coal-water slurry gasification that involves slurry preparation, burner, gasifier, slag melting and numerical simulation for plant design and operation were investigated. Entrained-flow gasification with coal water slurry can be used for synfuel production, SNG, chemicals as well as IGCC. To develop hybrid gasification process and use different types of coal, it is necessary to develop new technologies that will increase efficiency of the process.
[References]
  1. Takematsu T, Maude C, “Coal Gasification for IGCC Power Generation,” IEACR/37, March, 1991
  2. http://www.gasification.org.
  3. Higman C, van der Burgt M, “Gasification,” Elsevier, 2003
  4. Knoef HAM, “Handbook Biomass Gasification,” Gasnet, 2005
  5. Kim SD, “Coal Utilization and Conversion Technologies,” Minumsa, 1986
  6. Yang SM, Park WH, HWAHAK KONGHAK, 17(4), 305, 1979
  7. Ji PS, Park TJ, Kim JJ, Chem. Ind. Technol., 11(2), 76, 1993
  8. Lee J, Lee S, Korean Ind. Chem. News, 11(1), 26, 2008
  9. Senzou Y, et al., IHI Engineering Review, 25, 1, 1992
  10. Roh NS, Sin DH, Kim GH, Energy Engg., 3, 130, 1994
  11. Roh NS, Kim KH, Kim DC, HWAHAK KONGHAK, 33(3), 282, 1995
  12. DeVault RF, Shiao SY, Warchol JJ, Vecci SJ, "Characterization of Coals for Slurryability,” Technical Paper, RDTPA 85-34, Babcock & Wilcox Co., 15., 1985
  13. Ji Q, Hao A, Sun C, Wu J, “Coal Properties and Slurryability of Shenmu Coal,” Proc. of the 17th Int. Conf. on Coal Utilization & Slurry Technologies, Clearwater, Fla., April 28-May 1, 873-883, 1992
  14. Al Taweel AM, Fadaly O, Kwak JCT, Proc. of the 35th Can. Chem. Eng. Conf. C. S. Ch. E., Ottawa, Ontario, 1, 266, 1985
  15. Nishino J, Kiyama K, Seki M, J. Chem. Eng. Japan, 22, 162, 1989
  16. Shuquan Z, Zuna W, “The Influence of Oxygen Functional Groups in Coal on CWS Characteristics,” Proc. of the 16th Int. Conf. on Coal & Slurry Technologies, Clearwater, Fla., April 22-25, 447-458, 1991
  17. Roh NS, Sin DH, Kim GH, Kim DC, Energy Engg., 4, 163, 1995
  18. Yoon SJ, Choi YC, Lee JG, Korean J. Chem. Eng., 26(5), 1259, 2009
  19. Wilson WG, et al., Fuel Process. Technol., 15, 157, 1987
  20. Aiuchi K, Moriyama R, Takeda S, Kitada S, Onozaki M, Katayama Y, Fuel Process. Technol., 88(4), 325, 2007
  21. Kalmanovitch DP, Sanyal A, Williamson J, “A New Approach to Predicting the Slagging Propensity of a Coal Based on High Temperature Equilibria,” 3rd. International conference on slagging and fouling due to impurities in combustion gases, Cupper Mountain, Colorado, USA, 537-553, 1984
  22. Ashizawa M, CRIEPI report EW90003, 1990
  23. Hirato M, Ninomiya Y, Asami M, J. Fuel Society of Japan, 65, 670, 1986
  24. Hurst HJ, Novak F, Patterson JH, “Prediction of Calcium Carbonate Needed for Successful Slag Tapping of Some Astralian Coals in a Slagging Gasifier,” 6th Australian Coal Science Conference, Newcastle, 222, 1994
  25. Lee JG, Kim JH, Lee HJ, Park TJ, Kim SD, Kim JJ, Energy Engg., 4, 372, 1995
  26. Watt JD, Fereday F, J. Inst. Fuel, 42, 99, 1969
  27. Hoy HR, Robert AG, Wilkins DM, I.G.E.J., Comm., 672, 444, 1965
  28. Riboud PV, Roux Y, Lucas D, Gaye H, Fachberichte Huttenpraxis Metallweiter Verarbeitung, 19, 859, 1981
  29. Urbain G, Cambier F, Deletter M, Anseau MR, Trans. Brit. Ceramic Soc., 80, 35, 1981
  30. Jung BJ, Schobert HH, Energy Fuel, 6, 387, 1992
  31. Mills KC, “Slags - a Computer Program for Calculating Physio - Chemical Properties of Slags,” National Physical Laboratory, Teddington, UK, 1991
  32. Groen JC, Brooker DD, Welch PJ, Oh MS, Fuel Process. Technol., 56(1-2), 103, 1998
  33. Kim HB, Oh M, Ceramics International, 34, 2107, 2008
  34. Sowa W, “The Effect of Injector Design on the Performance of the Bringham Young University,” Ph.D. Thesis, Bringham Young University, 1987
  35. Sowa W, Fuel, 71, 593, 1992
  36. Erdmann C, Liebner W, Schlichting H, IchemE Gasification, Noordwijk, The Netherlands, 8-10 April, 2002
  37. Toporov HP, Stadler H, Tschunko S, Forster M, Kneer R, Fuel, 88, 1269, 2009
  38. Lee HJ, Park TJ, Kim JH, Lee JG, Ahn DH, Transactions of the KSME, 20, 1735, 1996
  39. Yoon SJ, Choi YC, Hong JC, Ra HW, Lee JG, Korean Chem. Eng. Res., 46(3), 561, 2008
  40. Choi YC, Liu XY, Park TJ, Kim JH, Lee JG, Fuel, 15, 2193, 2001
  41. Choi YC, Li XY, Park TJ, Kim JH, Lee JG, Korean J. Chem. Eng., 18(3), 376, 2001
  42. Liu XY, “Numerical Simulation of Coal Gasification,” Postdoc report, KIER, 1999
  43. Wen CY, Chaung T, “Entrained Coal Gasification Modeling," Indeng Chem process Des Dev 18., 1979
  44. Brwon BW, Smoot LD, Smith PJ, Hedman PO, AIChe J, 34, 435, 1988
  45. Watanabe H, Otaka M, Fuel, 85, 1935, 2006
  46. Chui EH, et al., Energy Procedia, 1, 503, 2009
  47. Jiradilok V, Gidaspow D, Breault RW, Shadle LJ, Guenther C, Shi SP, Chem. Eng. Sci., 63(8), 2135, 2008
  48. Phillips J., “Gasification Combined Cycles 101”, 2005 GTC, 2005
  49. Bissett LA, “An Engineering Assessment of Entrainment Gasification", US DOE, MERC/R1-7812, 1978
  50. Ryu SO, Kim JH, Lee HJ, Lee JG, Park TJ, Ahn DH, Park HY, Energy Engg., 6, 96, 1997
  51. Park TJ, Kim JH, Lee JG, Hong JC, Kim YG, Choi YC, Energy Engg., 8, 553, 1999
  52. Choi YC, Park TJ, Kim JH, Lee JG, Hong JC, Kim YG, Korean J. Chem. Eng., 18(4), 493, 2001