Issue
Korean Chemical Engineering Research,
Vol.47, No.3, 267-274, 2009
메탄의 건식 개질을 이용한 이산화탄소의 재활용
Recycle of Carbon Dioxide Using Dry Reforming of Methane
온실가스 배출 규제에 따라 이산화탄소 배출 감축은 산업계에서 해결해야 할 가장 중요한 과제 중 하나가 되었다. 이산화탄소는 온실가스 발생원 중 대부분을 차지하며 본 논문에서는 실제 대규모 산업 현장에서의 이산화탄소 배출을 저감하는 직접적인 방안으로 메탄의 이산화탄소 개질 반응을 이용하는 방법을 고찰해 보았다. 강한 흡열 반응 형태인 이 반응에 대해 추가적인 이산화탄소 발생을 피하며 효율적으로 에너지를 공급하기 위해서는 자열 개질 반응을 이용하는 것이 적합한 방법으로 판단된다. 생산된 합성가스는 환원가스로 재활용하거나 화학제품 및 연료의 합성에 활용 할 수 있다.
Considerable attention has been given to developing methodologies to reduce the emission of carbon dioxide from industry to meet strengthened environmental regulations. In this article, recent research trends on dry reforming of methane as an alternative method to reduce CO2 emission from large scale industrial processes are addressed. To efficiently provide the energy needed in this strong endothermic reaction without additional CO2 emission, it seems to be desirable to adopt autothermal reaction mode. The produced synthesis gas could be used as a reducing gas, or a feedstock for synthesis of chemicals and fuels.
[References]
  1. Kwon TH, Choi JY, Analysis on Recent Green House Gas Emission in Korea, Bank of Korea, Seoul, Korea, 2008
  2. IPCC, Cambridge, United Kingdom and New York, NY, USA, p. 442, 2005
  3. Song CS, Catal. Today, 115(1-4), 2, 2006
  4. Hu YH, Ruckenstein E, Catal. Rev.-Sci. Eng., 44(3), 423, 2002
  5. Bradford MCJ, Vannice MA, Catal. Rev.-Sci. Eng., 41(1), 1, 1999
  6. Hu YH, Ruckenstein E, Bruce CG, Helmut K, Advances in Catalysis, Academic Press, 2097, 2004
  7. Choudhary TV, Choudhary VR, Angewandte Chemie International Edition, 47, 1828, 2008
  8. Yagi F, Kanai R, Wakamatsu S, Kajiyama R, Suehiro Y, Shimura M, Catal. Today, 104(1), 2, 2005
  9. Pena MA, Gomez JP, Fierro JL, Appl. Catal. A: Gen., 144(1-2), 7, 1996
  10. http://www.ulcos.org/en/
  11. Moon KI, “Carbon Dioxide Reforming of Methane over Nickelbased Catalyst”, Department of Chemical Engineering, Pohang University of Science and Technology, Pohang, 111, 1996
  12. http://www.gms21.com
  13. Chubb TA, Solar Energy., 24, 341, 1980
  14. Rostrup-Nielsen J, Trimm DL, Journal of Catalysis, 48, 155, 1977
  15. Hu YH, Ruckenstein E, Catal. Lett., 43(1-2), 71, 1997
  16. Snoeck JW, Froment GF, Fowles M, J. Catal., 169(1), 240, 1997
  17. Ruckenstein E, Wang HY, J. Catal., 205(2), 289, 2002
  18. Bychkov VY, Tyulenin YP, Korchak VN, Kinetics and Catalysis, 44, 353, 2003
  19. Sierra Gallego G, Mondrag F, Tatibou JM, Barrault J, Batiot-Dupeyrat C, Catalysis Today, 133, 200, 2008
  20. Assabumrungrat S, Laosiripojana N, Piroonlerkgul P, J. Power Sources, 159(2), 1274, 2006
  21. Gadalla AM, Bower B, Chemical Engineering Science., 43, 3049, 1988
  22. Rostrup-Nielsen JR, Journal of Catalysis., 85, 31, 1984
  23. Rostrup-Nielsen JR, Calvin HB, John BB, Studies in Surface Science and Catalysis, Elsevier, 85, 1991
  24. Duprez D, DeMicheli MC, Marecot P, Barbier J, Ferretti OA, Ponzi EN, Journal of Catalysis., 124, 324, 1990
  25. Li L, Liu BS, Leung JWH, Au CT, Cheung ASC, Catalysis Today, 131, 533, 2008
  26. Laosiripojana N, Chadwick D, Assabumrungrat S, Chemical Engineering Journal., 138, 264, 2008
  27. Lima SM, Assaf JM, Pena MA, Fierro JLG, Appl. Catal. A: Gen., 311, 94, 2006
  28. Choudhary VR, Mondal KC, Mamman AS, J. Catal., 233(1), 36, 2005
  29. Fei JH, Hou ZY, Zheng XM, Yashima TS, Catal. Lett., 98(4), 241, 2004
  30. Bouarab R, Akdim O, Auroux A, Cherifi O, Mirodatos C, Appl. Catal. A: Gen., 264(2), 161, 2004
  31. Mattos LV, Rodino E, Resasco DE, Passos FB, Noronha FB, Fuel Process. Technol., 83(1-3), 147, 2003
  32. Seok SH, Choi SH, Park ED, Han SH, Lee JS, J. Catal., 209(1), 6, 2002
  33. Souza MMVM, Aranda DAG, Schmal M, J. Catal., 204(2), 498, 2001
  34. Xu ZL, Zhen M, Bi YL, Zhen KJ, Appl. Catal. A: Gen., 198(1-2), 267, 2000
  35. Seok SH, Department of chemical engineering, Pohang University of Science and Technology, Pohang, 133, 2000
  36. Kaengsilalai A, Luengnaruemitchai A, Jitkarnka S, Wongkasemjit S, J. Power Sources, 165(1), 347, 2007
  37. Ruckenstein E, Hu YH, Appl. Catal. A: Gen., 133(1), 149, 1995
  38. Ruckenstein E, Hu YH, Appl. Catal. A: Gen., 154(1-2), 185, 1997
  39. Tomishige K, Yamazaki O, Chen YG, Yokoyama K, Li XH, Fujimoto K, Catal. Today, 45(1-4), 35, 1998
  40. Valderrama G, Kiennemann A, Goldwasser MR, Catalysis Today, 133, 142, 2008
  41. Araujo GCD, Lima SMD, Assaf JM, Pe MA, Fierro JLG, do Carmo Rangel M, Catalysis Today, 133, 129, 2008
  42. Gallego GS, Mondragon F, Barrault J, Tatibouet JM, Batiot-Dupeyrat C, Appl. Catal. A: Gen., 311, 164, 2006
  43. Batiot-Dupeyrat C, Gallego GAS, Mondragon F, Barrault J, Tatibou JM, Catalysis Today, 107, 474, 2005
  44. Guo J, Lou H, Zhu Y, Zheng X, Materials Letters, 57, 4450, 2003
  45. Hayakawa T, Suzuki S, Nakamura J, Uchijima T, Hamakawa S, Suzuki K, Shishido T, Takehira K, Appl. Catal. A: Gen., 183(2), 273, 1999
  46. Tomishige K, Nurunnabi M, Maruyama K, Kunimori K, Fuel Process. Technol., 85(8-10), 1103, 2004
  47. Hou ZY, Gao J, Guo JZ, Liang D, Lou H, Zheng XM, J. Catal., 250(2), 331, 2007
  48. Souza MMVM, Schmal M, Appl. Catal. A: Gen., 281(1-2), 19, 2005
  49. Amin NAS, Yaw TC, International Journal of Hydrogen Energy, 32, 1789, 2007
  50. Liu SL, Xiong GX, Dong H, Yang WS, Appl. Catal. A: Gen., 202(1), 141, 2000
  51. Tomishige K, Kanazawa S, Suzuki K, Asadullah M, Sato M, Ikushima K, Kunimori K, Appl. Catal. A: Gen., 233(1-2), 35, 2002
  52. Choudhary VR, Mondal KC, Choudhary TV, Fuel, 85, 2484, 2006
  53. Choudhary VR, Mondal KC, Choudhary TV, Energy Fuels, 20(5), 1753, 2006
  54. Wei W, Stagg-Williams SM, Noronha FB, Mattos LV, Passos FB, Catal. Today, 98(4), 553, 2004
  55. Tomishige K, Matsuo Y, Yoshinaga Y, Sekine Y, Asadullah M, Fujimoto K, Appl. Catal. A: Gen., 223(1-2), 225, 2002
  56. O'Connor AM, Ross JRH, Catal. Today, 46(2-3), 203, 1998
  57. Mo LY, Zheng XM, Chan YH, Fei JH, React. Kinet. Catal. Lett., 78(2), 233, 2003
  58. Mo LY, Fei JH, Huang CJ, Zheng XM, J. Mol. Catal. A-Chem., 193(1-2), 177, 2003
  59. Jing QS, Lou H, Mo LY, Fei JH, Zheng XM, React. Kinet. Catal. Lett., 83(2), 291, 2004
  60. Guo JJ, Lou H, Zhao H, Chai DF, Zheng XM, Appl. Catal. A: Gen., 273(1-2), 75, 2004
  61. Gao J, Guo J, Liang D, Hou Z, Fei J, Zheng X, International Journal of Hydrogen Energy, 33, 5493, 2008
  62. Matsuo Y, Yoshinaga Y, Sekine Y, Tomishige K, Fujimoto K, Catal. Today, 63(2-4), 439, 2000
  63. Kunii D, Levenspiel O, Fluidization Engineering, Wiley, New York, 1969
  64. Santos A, Menendez M, Monzon A, Santamaria J, Miro EE, Lombardo EA, J. Catal., 158(1), 83, 1996
  65. Effendi A, Hellgardt K, Zhang ZG, Yoshida T, Catalysis Communications, 4, 203, 2003
  66. Chen X, Honda K, Zhang ZG, Appl. Catal. A: Gen., 288(1-2), 86, 2005
  67. Choudhary VR, Rajput AM, Prabhakar B, Catal. Lett., 32(3-4), 391, 1995
  68. Choudhary VR, Uphade BS, Mamman AS, Appl. Catal. A: Gen., 168(1), 33, 1998
  69. Ruckenstein E, Hu YH, Ind. Eng. Chem. Res., 37(5), 1744, 1998
  70. Song CS, Wei P, Catal. Today, 98(4), 463, 2004
  71. Choudhary VR, Mondal KC, Choudhary TV, Appl. Catal. A: Gen., 306, 45, 2006
  72. Larentis AL, de Resende NS, Salim VMM, Pinto JC, Appl. Catal. A: Gen., 215(1-2), 211, 2001
  73. Souza MMVM, Macedo Neto OIR, Schmal M, Journal of Natural Gas Chemistry, 15, 21, 2006
  74. Choudhary VR, Mamman AS, J. Chem. Technol. Biotechnol., 73(4), 345, 1998
  75. Ruckenstein E, Wang HY, Catal. Lett., 73(2-4), 99, 2001
  76. Ashcroft AT, Cheetham AK, Green MLH, Vernon PDF, Nature, 352, 225, 1991
  77. Pant B, Stagg-Williams SM, Catalysis Communications, 5, 305, 2004