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Issue
Korean Chemical Engineering Research,
Vol.45, No.6, 648-655, 2007
UV, H2O2, 오존을 이용한 고급산화공정에서의 테레프탈산 제조공정 폐수 처리 : 유기물 및 색도제거 연구
Advanced Oxidation Process for the Treatment of Terephthalic Acid Wastewater using UV, H2O2 and O3 : Organic and Color Removal Studies
권태옥, 박보배, 문일식
UV/H2O2, O3, O3/H2O2, UV/H2O2/O3 공정을 이용한 테레프탈산 제조공정 폐수의 COD 및 색도제거 연구를 수행하였다. UV/H2O2, O3, O3/H2O2, UV/H2O2/O3 공정에서의 COD 제거율은 각각 10, 48, 56, 63%, 색도 제거율은 UV/H2O2 공정이 80%, O3, O3/H2O2, UV/H2O2/O3 공정은 모두 99% 이상 효과적으로 제거되는 것으로 나타났다. COD 및 색도 제거율이 가장 우수한 UV/H2O2/O3 공정에서 테레프탈산 제조공정 폐수의 주요 유기물 성분인 테레프탈산, 이소프탈산 그리고 벤조산 성분은 120분 이내에 모두 99% 이상 제거되었다. 또한 UV/H2O2, O3/H2O2, UV/H2O2/O3 공정에서의 최적 H2O2 주입농도는 각각 0.5M, 25 mM 그리고 5 mM로 나타나, UV와 H2O2를 오존산화 공정에 조합함으로써 유기물 제거율 향상과 함께 사용된 H2O2의 저감효과를 동시에 얻을 수 있었다.
UV/H2O2, O3, O3/H2O2, UV/H2O2/O3 processes were tested for the removal of COD and color from terephthalic acid wastewater. COD removal efficiencies were 10, 48, 56, 63% in the UV/H2O2, O3, O3/H2O2, UV/H2O2/O3 process respectively. Color removal efficiency of UV/H2O2 process was 80% and O3, O3/H2O2, UV/H2O2/O3 processes were almost more than 99%. Terephthalic acid, isophthalic acid and benzoic acid were completely destructed in terephthalic wastewater within 120 min by UV/H2O2/O3 process and shows high COD and color removal efficiencies. The optimum concentration of H2O2 dosage was found to be 0.5 M, 25 mM and 5 mM for UV/H2O2, O3/H2O2 and UV/H2O2/O3 processes respectively, Organic destruction efficiency was enhanced and also reducing the consumption of H2O2 dosage by combining UV, H2O2 and O3 process.
Keywords: Terephthalic Acid; Benzoic Acid; Biorecalcitrant; Ozone; Advanced Oxidation Process
[References]
  1. Dai G, Cui L, Song L, Gong N, Chen J, Zhao R, Wang S, Chang HC, Wang X, Environ. Toxicol. Pharmacol., 20(1), 209, 2005
  2. Zhang XX, Cheng SP, Wan YQ, Sun SL, Zhu CJ, Zhao DY, Pan WY, Int. Biodeterior. Biodegrad., 58(2), 94, 2006
  3. Wang QB, Xu HB, Li X, Fluid Phase Equilib., 233(1), 81, 2005
  4. Wen YZ, Tong SP, Zheng KF, Wang LL, Lv JZ, Lin J, J. Hazard. Mater. B, 138(1), 169, 2006
  5. Ryu WR, Cho MH, Choi JS, Yang YW, J. KSEE, 20(7), 927, 1998
  6. Kang DZ, Hong YP, Lee JH, Kor. J. Microbiol. Biotechnol., 31(2), 177, 2003
  7. Kim JH, Rhee CH, Woo CJ, Joo GJ, Seo SK, Park HD, Kor. J. Appl. Microbiol. Biotechnol., 27(2), 118, 1999
  8. Wang J, Chen L, Shi H, Qian Y, Chemosphere, 41(8), 1245, 2000
  9. Suh SK, Kor. J. Env. Hlth. Soc., 27(3), 43, 2001
  10. Kaneco S, Katsumata H, Suzuki T, Ohta K, Chem. Eng. J., 125(1), 59, 2006
  11. Lee SM, Jo HJ, Kim JG, Jung JH, J. KSWQ, 20(5), 452, 2004
  12. Ahn SH, Joung SN, Yoo KP, Noh MJ, Han JH, Han SH, Korean J. Chem. Eng., 15(4), 390, 1998
  13. Park TJ, Lim JS, Lee YW, Kim SH, J. Supercrit. Fluids, 26(3), 201, 2003
  14. Lee JW, Chung SJ, Balaji S, Kokovkin VV, Moon IS, Chemosphere, 68(6), 1067, 2007
  15. Balaji S, Kokovkin VV, Chung SJ, Moon IS, Water Res., 41, 1423, 2007
  16. Matheswaran M, Balaji S, Chung SJ, Moon IS, J. Ind. Eng. Chem., 13(2), 231, 2007
  17. Balaji S, Chung SJ, Manickam M, Ramesh T, Moon, IS, Water Sci. Technol., 55(1-2), 261, 200
  18. Balaji S, Chung SJ, Matheswaran M, Moon IS, Korean J. Chem. Eng., 24(6), 1009, 2007
  19. Kokovkin VV, Chung SJ, Balaji S, Matheswaran M, Moon IS, Korean J. Chem. Eng., 24(5), 749, 2007
  20. Jun JC, Kwon TO, Moon IS, Korean J. Chem. Eng., In press, 2007
  21. Kwon TO, Park BB, Moon IS, J. Korean Ind. Eng. Chem., In press, 2007
  22. Thiruvenkatachari R, Kwon TO, Moon IS, Korean J. Chem. Eng., 22(6), 938, 2005
  23. Ramesh T, Kwon TO, Jun JC, Balaji S, Matheswaran M, Moon IS, J. Hazard. Mater., 142(1-2), 308, 2006
  24. Andreozzi R, Marotta R, Water Res., 38(5), 1225, 2004
  25. Taborda AV, Brusa MA, Grela MA, Appl. Catal. A: Gen., 208(1-2), 419, 2001
  26. Ramesh T, Kwon TO, Moon IS, J. Environ. Sci. Health Part A, 41(8), 1685, 2006
  27. Guzzella L, Feretti D, Monarca S, Water Res., 36(17), 4307, 2002
  28. Maldonado MI, Malato S, Perez-Estrada LA, Gernjak W, Oller I, Domenech X, Peral J, J. Hazard. Mater., 138(2), 363, 2006
  29. Kurniawan TA, Lo WH, Chan GYS, J. Hazard. Mater., 137(1), 443, 2006
  30. Behnajady MA, Modirshahla N, Fathi H, J. Hazard. Mater., 136(3), 816, 2006
  31. Hwang SC, Bouwer EJ, Larson SL, Davis JL, J. Hazard. Mater., 108(1-2), 61, 2004
  32. Azbar N, Yonar T, Kestioglu K, Chemosphere, 55(1), 35, 2004
  33. Jung JH, Suh H, Mohseni M, Water Res., 38(10), 2596, 2004
  34. Balcioglu IA, Otker M, Chemosphere, 50(1), 85, 2003
  35. Esplugas S, Gimenez J, Contreras S, Pascual E, Rodriquez M, Water Res., 36(4), 1034, 2002
  36. Heredia JB, Torregrosa J, Dominquez JR, Peres JA, Chemosphere, 42(4), 351, 2001
  37. Lee CG, Kim MC, J. Korean Ind. Eng. Chem., 16(3), 366, 2005
  38. Langlais B, Reckhow DA, Brink DR, Ozone in water Freatment Application and Enineering, Lewis Publishers, Inc., USA, 1991
  39. Wu D, Liu M, Dong D, Zhou X, Microchem J., 85(2), 250, 2007
  40. Diagne M, Oturan N, Oturan MA, Chemosphere, 66(5), 841, 2007
  41. Klan P, Vavrik M, J. Photochem. Photobiol. A-Chem., 177(1), 24, 2006
  42. Matykiewiczova N, Kurkova R, Klanova J, Klan P, J. Photochem. Photobiol. A-Chem., 187(1), 24, 2007
  43. Eftaxias A, Font J, Fortuny A, Fabregat A, Stuber F, Appl. Catal. B: Environ., 67(1-2), 12, 2006
  44. Moctezuma E, Leyva E, Palestino G, Lasa HD, J. Photochem. Photobiol. A-Chem., 186(1), 71, 2007
  45. Kim JS, J. Korean Solid Wastes Engineering Society, 15(6), 660, 1998
  46. El-Din M, Smith DW, Monami FA, Wang W, Water Res., 40(2), 392, 2006
[Cited By]
  1. Jung JA, Kwak DH, Oh DW, Park DM, Yang OB, Korean Chemical Engineering Research, 50(1), 11, 2012
  2. Muthuraman G, Moon IS, Journal of Industrial and Engineering Chemistry, 18(5), 1540, 2012
  3. Kwon SC, Kim JY, Yoon SM, Bae W, Kang KS, Rhee YW, Journal of Industrial and Engineering Chemistry, 18(6), 1951, 2012
  4. Mohammed L, Won JH, Kim YJ, Ko JM, Song KH, Lee CH, Korean Chemical Engineering Research, 51(4), 523, 2013
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