Issue
Korean Chemical Engineering Research,
Vol.45, No.6, 536-546, 2007
기상 공정에 의한 나노 미립자 제조
Preparation of Nanoparticles by Gas Phase Processes
나노 미립자는 부피대비 높은 표면적을 가지고 있기 때문에 벌크 상태에서는 볼 수 없는 여러 흥미로운 성질들을 가지고 있다. 나노 미립자들은 나노 구조체 재료, 산업용 재료 혹은 촉매 재료 등을 제조하는데 사용될 수 있다. 기상공정에 의해 높은 단분산성을 갖는 다양한 크기의 나노 미립자를 제조할 수 있으며 제조된 미립자는 각종 첨단 기능성 재료의 원료로 이용될 수 있다. 본고에서는 기상공정을 통하여 나노 미립자 제조에 이용되는 에어로솔 반응기들을 소개하였으며 각 반응기의 특성을 분석하였고 기상 공정에 의한 미립자 제조에 관련된 최근 흥미 있는 연구들을 소개하도록 하였다.
The nanoparticles have several interesting properties which cannot be shown in their bulk materials because of their high ratio of surface area to volume. They can be used to manufacture the nanostructured materials, the industrial materials, or the catalyst materials etc.. We can prepare nanoparticles of various sizes with high degree of monodispersity by gas phase processes and those particles can be used as raw materials for various advanced functional materials. In this paper, we introduced the aerosol reactors to synthesize nanoparticles by gas phase processes and also analyzed several features of those aerosol reactors and tried to introduce the recent interesting studies on nanoparticle synthesis by gas phase processes.
[References]
  1. http://www.ptl.ethz.ch/people/director/pratsinis/index
  2. Kim DS, Kim TO, Fine Particle Technology, 2001
  3. Gotoh K, Masuda H, Higashitani K, Power Technology Handbook, 2nd ed., Marcel Dekker, New York, 1997
  4. Young RM, Pfender E, Plasma Chem. Plasma Process., 5(1), 1, 1985
  5. Pratsinis SE, Vemury S, Powder Technol., 88(3), 267, 1996
  6. Kruis FE, Fissan H, Peled A, J. Aerosol Sci., 29(5-6), 511, 1998
  7. Choi M, J. Nanopart. Res., 3(2-3), 201, 2001
  8. Pratsinis SE, Mastrangelo SVR, Chem. Eng. Prog., 85(5), 62, 1989
  9. Friedlander SK, Smoke, Dust and Haze, Wiley, New York, 1977
  10. Seinfeld JH, Atmospheric Chemistry and Physics of Air Pollution, Wiely, New York, 1986
  11. Kim MC, Bae GN, Moon KC, Park JY, J. Korean Soc. Atmos. Environ., 20(2), 161, 2004
  12. Jeon KJ, Jung YW, Powder Technol., 141(1-2), 1, 2004
  13. Kim KS, Pratsinis SE, AIChE J., 34(6), 912, 1988
  14. Wu JJ, Flagan RC, J. Appl. Phys., 61(4), 1365, 1987
  15. Morooka S, Kobata A, Umeda T, Kusakabe K, J. Chem. Eng. Jpn., 22(1), 94, 1989
  16. Scheibel HG, Porstendorfer J, J. Aerosol Sci., 14(2), 113, 1983
  17. Kruis FE, Goossens A, Fissan H, J. Aerosol Sci., 27(S1), S165, 1996
  18. Nakaso K, Okuyama K, Shimada M, Pratsinis SE, Chem. Eng. Sci., 58(15), 3327, 2003
  19. Choi JG, Park KY, J. Nanopart. Res., 8(2), 269, 2006
  20. Kim KS, AIChE J., 43(11), 2679, 1997
  21. Hyun BS, Kim KS, HWAHAK KONGHAK, 33(2), 183, 1995
  22. Paradise M, Goswami T, Mater. Des., 28(5), 1477, 2007
  23. Barreiro A, Kramberger C, Rummeli MH, Gruneis A, Grimm D, Hampel S, Gemming T, Buchner B, Bachtold A, Pichler T, Carbon, 45(1), 55, 2007
  24. Ulrich GD, Combust. Sci. Technol., 4(1), 47, 1971
  25. Wood DL, Potkay E, Clark HR, Kometani TY, Appl. Spectrosc., 42(2), 299, 1988
  26. Chae BS, Kim KS, HWAHAK KONGHAK, 37(6), 821, 1999
  27. Wegner K, Pratsinis SE, Powder Technol., 150(2), 117, 2005
  28. Ahn KH, Sohn SH, Jung CH, Choi M, Scripta Mater., 44(8-9), 1889, 2001
  29. Vander Wal RL, Ticich TM, Curtis VE, Chem. Phys. Lett., 323(3-4), 217, 2000
  30. Height MJ, Howard JB, Tester JW, Vander Sande JB, Carbon, 42(11), 2295, 2004
  31. Kim KH, Lee IH, Kim KS, Kim DJ, Prospect. Ind. Chem., 8(6), 56, 2005
  32. Girshik SL, Chiu CP, McMurry PH, Plasma Chem. Plasma Process., 8(2), 145, 1988
  33. Rhee SW, Park HS, Sci. Technol. Ceram. Mater., 3(4), 309, 1988
  34. Oh SM, Park DW, Thin Solid Films, 386(2), 233, 2001
  35. Hong SH, Phys. High Technol., 7(9), 27, 1998
  36. Seo JH, Kim DU, Nam JS, Hong SH, Sohn SB, Song SM, J. Am. Ceram. Soc., 90(6), 1717, 2007
  37. Mizuguchi Y, Kagawa M, Suzuki M, Syono Y, Hirai T, Nanostruct. Mater., 4(5), 591, 1994
  38. Kim KS, Kim DJ, J. Appl. Phys., 87(6), 2691, 2000
  39. Kim DJ, Kim KS, AIChE J., 48(11), 2499, 2002
  40. Kim KS, Kim DJ, Yoon JH, Park JY, Watanabe Y, Shiratani M, J. Colloid Interface Sci., 257(2), 195, 2003
  41. Kim DJ, Kim KS, Zhao QQ, J. Nanopart. Res., 5(3-4), 211, 2003
  42. Shiratani M, Fukuzawa T, Watanabe Y, Jpn. J. Appl. Phys., 38(7B), 4542, 1999
  43. McCurdy PR, Truitt JM, Fisher ER, J. Vac. Sci. Technol. A, 17(5), 2475, 1999
  44. Madan A, Morrison S, Sol. Energy Mater. Sol. Cells, 55(1), 127, 1998
  45. Kim DJ, Kim KS, Ind. Eng. Chem. Res., 44(21), 7907, 2005
  46. Kim KS, Kim DJ, Zhao QQ, Chem. Eng. Sci., 61(10), 3278, 2006
  47. Matsui I, J. Nanopart. Res., 8(3-4), 429, 2006
  48. Kim K, Cho Y, Kim Y, Kim T, Proceedings of 2007 ASME International Mechanical Engineering Congress and Exposition (IMECE2007), Nov. Seattle, Washington, USA, 2007
  49. Cao J, Matsoukas T, J. Nanopart. Res., 6(5), 447, 2004
  50. Barankin MD, Creyghton Y, Schmidt-Ott A, J. Nanopart. Res., 8(3-4), 511, 2006
  51. Hoder T, Kudrle V, Frgala Z, Janca J, WDS’05 Proceedings of Contributed Papers, Part II, 300-305, 2005
  52. Iwama S, Hayakawa K, Arizumi T, J. Cryst. Growth, 56(2), 265, 1982
  53. Gunther B, Kumpmann A, Nanstruct. Mater., 1(1), 27, 1992
  54. Saunders WA, Sercel PC, Lee RB, Atwater HA, Vahala KJ, Flagan RC, Escorcia-Aparcio EJ, Appl. Phys. Lett., 63(11), 1549, 1993
  55. Kim HJ, Kim JH, Choi YJ, Oh HC, Chu JB, Kim SS, J. Mech. Sci. Technol., 20(11), 1972, 2006
  56. Byeon JH, Park JH, Yoon KY, Ko BJ, Ji JH, Hwang, J, Carbon, 44(10), 2106, 2006
  57. Guo Z, Du F, Yu S, J. Nanopart. Res., 7(1), 95, 2005
  58. Cui ZL, Zhang ZK, Hao CC, Dong LF, Meng ZG, Yu LY, Thin Solid Films, 318(1-2), 76, 1998
  59. Cannon WR, Danforth SC, Haggerty JS, Murra RA, J. Am. Ceram. Soc., 65(7), 330, 1982
  60. Cauchetier M, Croix O, Luce M, Michon M, Paris J, Tistchenko S, Ceram. Int., 13(1), 13, 1987
  61. Alexandrescu R, Dumitrache F, Morjan I, Sandu I, Savoiu M, Voicu I, Fleaca C, Piticescu R, Nanotechnology, 15(5), 537, 2004
  62. Leconte Y, Maskrot H, Combemale L, Herlin-Boime N, Reynaud C, J. Anal. Appl. Pyrolysis, 79(1-2), 465, 2007
  63. Jang D, Kim D, Appl. Phys. A-Mater. Sci. Process., 79(8), 1985, 2004
  64. Noel S, Hermann J, Itina T, Appl. Surf. Sci., 253(15), 6310, 2007
  65. Dammer O, Blanka Vlckova B, Slouf M, Pfleger J, Mater. Sci. Eng. B-Solid State Mater. Adv. Technol., 140(3), 138, 2007
  66. Gurav A, Kodas T, Pluym T, Xiong Y, Aeosol Sci. Technol., 19(4), 411, 1993
  67. Siegel RW, Morfin-Lopez JL, Sanchez JM, Advanced Topics in Materials Science and Engineering, Plenum, New York, 1993
  68. Jung CH, Park SH, Kim YP, J. Aerosol Sci., 37(10), 1400, 2006
  69. Tasaki A, Tomiyama S, Iida S, Wada N, Uyeda R, Jpn. J. Appl. Phys., 4(10), 707, 1965
  70. Chow GM, Klemens PG, Strutt PR, J. Appl. Phys., 66(7), 3304, 1989
  71. Hahn H, Averback RS, J. Appl. Phys., 67(2), 1113, 1990
  72. Yamada I, Usui H, Takagi, T, J. Phys. Chem., 91(10), 2463, 1987
  73. Bowles RS, Kolstad JJ, Calo JM, Andres RP, Surf. Sci., 106(1-3), 117, 1981
  74. Bayazitoglu Y, Brotzen FR, Zhang Y, Nanostruct. Mater., 7(7), 789, 1996
  75. Abdullah M, Iskandar F, Shibamoto S, Ogi T, Okuyama K, Acta Mater., 52(17), 5151, 2004
  76. Kang DJ, Kim KN, Kim SG, J. Mater. Sci., 40(23), 6283, 2005
  77. Kang YC, Park SB, J. Mater. Sci. Lett., 16(2), 131, 1997
  78. Wang WN, Itoh Y, Lenggoro IW, Okuyama K, Mater. Sci. Eng. B-Solid State Mater. Adv. Technol., 111(1), 69, 2004
  79. Wang WN, Lenggoro IW, Terashi Y, Kim TO, Okuyama K, Mater. Sci. Eng. B-Solid State Mater. Adv. Technol., 12(3), 194, 2005
  80. Xia B, Lenggoro IW, Okuyama K, Adv. Mater., 13(20), 1579, 2001
  81. Lee SG, Choi SM, Lee D, Thermochim. Acta, 455(1-2), 138, 2007
  82. Mueller R, Madler L, Pratsinis SE, Chem. Eng. Sci., 58(10), 1969, 2003
  83. Strobel R, Krumeich F, Stark WJ, Pratsinis SE, Baiker A, J. Catal., 222(2), 307, 2004
  84. Jang HD, Chang H, Suh Y, Okuyama K, Curr. Appl. Phys., 6(S1), e110, 2006
  85. Tang KQ, Gomez A, J. Colloid Interface Sci., 184(2), 500, 1996
  86. Lenggoro IW, Okuyama K, de la Mora JF, Tohge N, J. Aerosol Sci., 31(1), 121, 2000
  87. Cole RB, Electrospray Ionization Mass Spectroscopy, Wiley-Interscience, 1997
  88. Park H, Kim K, Kim SS, J. Aerosol Sci., 35(11), 1295, 2004
  89. Wilhelm O, Madler L, Pratsinis SE, J. Aerosol Sci., 34(7), 815, 2003
  90. Nakasoa K, Han B, Ahn KH, Choi M, Okuyama K, J. Aerosol Sci., 34(7), 869, 2003
  91. Jung J, Perrut M, J. Supercrit. Fluids, 20(3), 179, 2001
  92. Pack JW, Kim SH, Park SY, Lee YW, Kim YH, Macromolecules, 37(10), 3564, 2004
  93. Fages J, Lochard H, Letourneau JJ, Sauceau M, Rodier E, Powder Technol., 141(3), 219, 2004
  94. Rodrigues M, Peirio N, Matos H, Gomes de Azevedo E, Lobato MR, Almeida AJ, J. Supercrit. Fluids, 29(1-2), 175, 2004