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Issue
Korean Chemical Engineering Research,
Vol.45, No.5, 424-432, 2007
바이오디젤 공정기술과 연료특성
Biodiesel Production Technology and Its Fuel Properties
홍연기, 홍원희
바이오디젤은 식물유지 및 동물유지와 같은 재생 가능한 자원으로부터 얻어지는 친환경 대체에너지로서 주목받고 있다. 바이오디젤은 식물유지 또는 동물성 지방으로부터 얻어지는 긴사슬 지방산의 모노알킬에스터이다. 본 총설에서는 (1) 바이오디젤을 얻기위한 전이에스테로화 반응에 대한 촉매의 타입, 자유지방산 및 수분, 알콜과 유지의 반응비, 알콜타입, 반응온도 및 시간과 교반강도의 영향, (2) 전이에스테르화 이후의 바이오디젤에 대한 분리공정, 그리고 (3) 대체에너지로서 바이오디젤의 내연기관 적합성을 바이오디젤의 물성에 기초하여 소개한다.
Biodiesel is gaining more attractive due to its eco-friendly and the fact that it is prepared from renewable sources. It is monoalkyl esters of long chain fatty acids derived from vegetable oils and animal fats via transesterification reaction with alcohol in the presence of catalyst. This paper will review briefly (1) the effect of reaction conditions such as catalyst type, amount of free fatty acid and moisture, molar ratio of alcohol and oil, alcohol type, reaction temperature and time and stirring intesity, (2) downstream process of biodiesel after transesterification reaction, and (3) potentialities of biodiesel as an alternative fuel based on its properties in diesel engines.
Keywords: Biodiesel; Transesterification; Vegetable Oil; Cloud Point; Oxidative Stability
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  2. Song SH, Lee SH, Park DR, Kim HS, Woo SY, Song WS, Kwon MS, Song IK, Korean Journal of Chemical Engineering, 26(2), 382, 2009
  3. Lim YK, Kim DK, Yim ES, Journal of the Korean Industrial and Engineering Chemistry, 20(2), 208, 2009
  4. Lim YK, Jeon CH, Kim S, Yim ES, Song HO, Shin SC, Kim DK, Korean Chemical Engineering Research, 47(2), 237, 2009
  5. Song SH, Lee SH, Park DR, Kim H, Woo SY, Song WS, Kwon MS, Song IK, Korean Journal of Chemical Engineering, 26(6), 1539, 2009
  6. Lee SB, Lee JD, Journal of the Korean Industrial and Engineering Chemistry, 20(5), 532, 2009
  7. Hong JS, Kim YW, Chung KW, Jeong SH, Applied Chemistry for Engineering, 21(5), 542, 2010
  8. Lim SM, Shin HY, Oh SC, Bae SY, Applied Chemistry for Engineering, 21(2), 174, 2010
  9. Choi JH, Park YB, Lee SH, Cheon JK, Woo HC, Korean Chemical Engineering Research, 48(5), 583, 2010
  10. Choi JH, Park YB, Lee SH, Cheon JK, Choi JW, Woo HC, Korean Chemical Engineering Research, 48(5), 643, 2010
  11. Lim YK, Park SR, Kim JR, Yim ES, Jung CS, Applied Chemistry for Engineering, 21(6), 684, 2010
  12. Jeon DJ, Yeom SH, Korean Journal of Chemical Engineering, 27(5), 1555, 2010
  13. Lee SB, Lee JD, Hong IK, Journal of Industrial and Engineering Chemistry, 17(1), 138, 2011
  14. Jeon DJ, Yeom SH, Korean Journal of Chemical Engineering, 28(6), 1420, 2011
  15. Choi JM, Yeom SH, Korean Journal of Chemical Engineering, 28(11), 2170, 2011
  16. Kim SM, Kim DK, Lee JS, Park SC , Rhee YW, Clean Technology, 18(1), 102, 2012
  17. Hong JS, Chung KW, Kim YW, Kim NK, Im DJ, Applied Chemistry for Engineering, 23(2), 232, 2012
  18. Yuk JS, Kim YW, Yoo SH, Chung KW, Kim NK, Lim DJ, Applied Chemistry for Engineering, 23(4), 421, 2012
  19. Hong YK, Korean Chemical Engineering Research, 50(5), 759, 2012
  20. Kim M, Lee HS, Shin YH, Ahn KH, Youn YS, Kim J, Lee YW, Korean Journal of Chemical Engineering, 29(10), 1289, 2012
  21. Choi JH, Lee SD, Woo HC, Clean Technology, 19(4), 416, 2013
  22. Lee SJ, Kim YW, Yoo SH, Kim NK, Shin JH, Yoon BT, Applied Chemistry for Engineering, 24(5), 530, 2013
  23. Kang H, Song H, Ha J, Na BK, Korean Journal of Chemical Engineering, 33(7), 2084, 2016
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