Issue
Korean Chemical Engineering Research,
Vol.42, No.4, 471-476, 2004
퇴비를 이용한 플라스틱의 호기성 생분해도 측정
Determination of Aerobic Biodegradability of Plastic Materials using Compost
동물 사료를 퇴비화한 퇴비를 이용하여 플라스틱의 생분해도를 KS M 3100-1(2002)의 규격에 의거하여 측정하였을 때 평가 결과의 재현성을 반복 실험을 통하여 조사하였다. 퇴비로부터의 이산화탄소 발생은 실험을 3회 반복하더라도 상호 유사한 거동을 나타내었다. Polycaprolactone(PCL)과 poly(butylene succinate-co-butylene adipate)(PBSA)에 대한 생분해도 측정을 동물 사료 퇴비를 이용하여 행한 결과 제조 날짜가 다른 퇴비를 사용하였을 때 생분해 10-35일 사이에는 생분해도가 약간 다르게 나타났으나 최종 생분해도는 상효 유사하여 퇴비를 이용한 플라스틱의 생분해도는 훌륭한 재현성을 보였다.
Biodegradability of plastics was evaluated according to KS M3100-1(2002) and reproducibility of the evaluation results was examined using a compost made from an animal fodder composting. Amount of CO2 produced from the compost exhibited almost the same trend in the three times of the repeated experiments. Biodegradability of polycaprolactone(PCL) and poly(butylene succinate-co-butylene adipate)(PBSA) was carried out by using the compost and it appeared slightly different during 10-35 days after the onset of the biodegradation test depending on the compost production date. However the final biodegradability was almost identical in the repeated experiments indicating that the biodegradation test can be realized in the compost with an excellent reproducibility.
[References]
  1. Ernst T, Popp R, Eldik RV, Talanta, 53(2), 347, 2000
  2. Li CT, Zhuang HK, Hsieh LT, Lee WJ, Tsao MC, Environmental International, 27(1), 61, 2001
  3. Colin G, Cooney JD, Carlsson DJ, Wiles DM, J. Appl. Polym. Sci., 26(2), 509, 1981
  4. ASTM D5209-92, "Standard Test Method for Determining the Aerobic Biodegradation of Plastic Materials in the Presence of Municipal Sewage Sludge," Annual Book of ASTM Standards, Vol. 08-03, American Society for Testing and Materials, Philadelphia, U.S.A, 08-03, 1992
  5. ASTM D5247-92, "Standard Test Method for Determining the Aerobic Biodegradability of Degradable Plastic by Spedific Microorganisms," Annual Book of ASTM Standards, Vol. 08-03, American Society for Testing and Materials, Philadelphia, U.S.A, 08-03, 1992
  6. Fields RD, Rodirguez P, Finn RK, J. Appl. Polym. Sci., 18(12), 3571, 1974
  7. ASTM D5338-92, "Standard Test Method for Determining the Aerobic Biodegradation of Plastics Materials Under Controlled Composting Condition," Annual Book of ASTM Standards, Vol. 08-03, American Society for Testing and Materials, Philadelphia, U.S.A, 08-03, 1992
  8. Johnson KE, Pometto III AL, Nikolov Z, Appl. Environ. Microbiol., 59(4), 1155, 1993
  9. ASTM D5210-91, "Standard Test Method for Determining the Anaerobic Biodegradation of Plastics Materials in the Presence of Municipal Sewage Sludge," Annual Book of ASTM Standards, Vol. 08-03, American Society for Testing and Materials, Philadelphia, U.S.A, 1991
  10. Tokiwa Y, Iwamoto A, Koyama M, Polym. Mater. Sci. Eng., 63, 742, 1990
  11. KS M 3100-1:2002(MOD ISO 14855:1999) "Determination of the Ultimate Aerobic Biodegradability and Disintegration of Plastic Materials Under Controlled Composting Conditions-Part 1: Analysis of Evolved Carbon Dioxide by Titration Method," Seoul, 2002
  12. International Standard ISO 14855:1999(E), "Determination of the Ultimate Aerobic Biodegradability and Disintegration of Plastic Materials Under Controlled Composting Conditions - Method by Analysis of Evolved Carbon Dioxide," Geneva, Switzerland, 1999
  13. Ohtaki A, Sato N, Nakasaki K, Polym. Degrad. Stabil., 61(3), 499, 1998
  14. Bernal MP, Sanchez-Monedero MA, Paredes C, Roig A, Agric. Ecosyst. Environ., 69(3), 175, 1998
  15. Fang M, Wong JWC, Ma KK, Wong MH, Bioresour. Technol., 67(1), 19, 1999
  16. Park JB, Kim YS, Choi SS, Hur HW, Han SH, J. Kor. Solid Wastes Engineering Society., 18, 559, 2001
  17. Ratto JA, Stenhouse PJ, Auerbach M, Mitchell J, Farrell R, Polymer, 40(24), 6777, 1999
  18. Ohtaki A, Akakura N, Nakasaki K, Polym. Degrad. Stabil., 62(2), 279, 1998