Process modeling and simulation is a powerful methodology to quantitatively predict the change of process variables when operating and design conditions are changed. In this study, considering drawbacks of currently used process simulator for combined cycle plants, we developed process modeling system equipped with an ease of use and flexibility for model development. For this purpose, the analysis of combined cycle processes was carried out and consequently, mathematical models and libraries were developed. Furthermore, in view of the fact that the level of the abstraction of process models depends on the purpose of simulation as well as the available data, simple and rigorous models were also developed for some important units. In use of reference combined plant, we executed process simulation using the developed modeling system and the comparison was made between the results of simulation and the reference data. Less than 1% marginal error was identified and we concluded that the modeling system can be applied for commercial combined cycle processes.